Investigation of the interactions of polyvinylpyrrolidone with mixtures of anionic and nonionic surfactants or anionic and zwitterionic surfactants by pulsed field gradient NMR

Misselyn-Bauduin, Anne-Marie; Thibaut, André; Grandjean, Jean; Broze, Guy; Jérôme, Robert

doi:10.1006/jcis.2001.7451

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Investigation of the interactions of polyvinylpyrrolidone with mixtures of anionic and nonionic surfactants or anionic and zwitterionic surfactants by pulsed field gradient NMR

Misselyn-Bauduin, Anne-Marie; Thibaut, André; Grandjean, Jean et al.

2001 • In Journal of Colloid and Interface Science, 238 (1), p. 1-7

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/11913

DOI
10.1006/jcis.2001.7451

PubMed
11350128

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Abstract :

[en] The interaction of polyvinylpyrrolidone (PVP) with an anionic surfactant (sodium dodecyl sulfate, SDS), a nonionic surfactant (pentaethylene glycol monodecyl ether, C(10)E(5)), and a zwitterionic surfactant (lauryl amido propyl betaine, LAPB) has been investigated by means of pulsed gradient spin-echo NMR (FT-PGSE NMR), allowing self-diffusion coefficients to be determined. The results confirm the strong interaction prevailing in the PVP/SDS system, whereas no association has been observed in the PVP/C(10)E(5) and PVP/LAPB systems. Mixing PVP with two surfactants, namely SDS and C(10)E(5) or SDS and LAPB, results in the formation of ternary aggregates between the polymer and the mixed micelles.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Misselyn-Bauduin, Anne-Marie; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Thibaut, André ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Grandjean, Jean ; Université de Liège - ULiège > Department of Chemistry > Chimie organique et spectroscopie multinucléaire (COSM)

Broze, Guy ; Colgate Palmolive, Milmort (Herstal), Belgium

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Investigation of the interactions of polyvinylpyrrolidone with mixtures of anionic and nonionic surfactants or anionic and zwitterionic surfactants by pulsed field gradient NMR

Publication date :

01 June 2001

Journal title :

Journal of Colloid and Interface Science

ISSN :

0021-9797

eISSN :

1095-7103

Publisher :

Academic Press, Orlando, United States - Florida

Volume :

238

Issue :

Pages :

1-7

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6WHR-45B64WN-FK-1&_cdi=6857&_user=532038&_orig=browse&_coverDate=06%2F01%2F2001&_sk=997619998&view=c&wchp=dGLbVzb-zSkzV&md5=9ac9a2b2102d4eb8f0177229c8980599&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/622861/description#description

Funders :

BELSPO - Politique scientifique fédérale
Colgate Palmolive Company

Commentary :

The authors acknowledge Journal of Colloid & Interface Science (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 27 April 2009

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