Reference : Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorin...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/10959
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide
English
Grignard, Bruno [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Calberg, Cédric mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Mar-2008
European Polymer Journal
Elsevier Science
44
3
861-871
Yes (verified by ORBi)
International
0014-3057
[en] green technology ; green technology ; radical polymerization ; atom transfer radical polymerization (ATRP) ; (meth)acrylate
[en] Macromolecular fluorinated ligands were prepared according to a three-step strategy that consists of the random copolymerization of heptadecafluorodecyl acrylate and 2-hydroxyethylacrylate, followed by the esterification of the pendant hydroxyl groups with acryloyl chloride and the Michael-type addition of tetraethyldiethylenetriamine onto the acrylic double bonds of the polymeric chains. These fluorinated macroligands were successfully used in the atom transfer radical polymerization of MMA catalyzed by a copper salt in a fluorinated solvent. The polymerization control was analyzed in relation to the copper salt, the initiator and the molecular weight and composition of the macroligand before being extended to the heterogeneous ATRP of MMA in scCO2.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers
http://hdl.handle.net/2268/10959
10.1016/j.eurpolymj.2007.11.020
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TWW-4R7NR85-1-T&_cdi=5573&_user=532038&_orig=browse&_coverDate=03%2F31%2F2008&_sk=999559996&view=c&wchp=dGLzVlz-zSkWA&md5=db0476a2ab4e442b4b0707f60df0c7e0&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/294/description#description
The authors acknowledge European Polymer Journal (Elsevier) for allowing them to archive this paper.

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