Reference : Controlled radical (co)polymerisation of allylic- and vinylic monomers originating fr...
Scientific congresses and symposiums : Unpublished conference/Abstract
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/224574
Controlled radical (co)polymerisation of allylic- and vinylic monomers originating from renewable resources
English
Scholten, Philip [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > Karlsruhe Institute of Technology (KIT), Institute of Organic Chemistry (IOC), Germany > > >]
Demarteau, Jérémy [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
Gennen, Sandro [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
De Winter, Julien [University of Mons, Organic Synthesis and Mass Spectrometry Laboratory, Belgium > > > >]
Grignard, Bruno [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
Debuigne, Antoine mailto [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
Meier, Michael A. R. [Karlsruhe Institute of Technology (KIT), Institute of Organic Chemistry (IOC), Germany > > > >]
Detrembleur, Christophe mailto [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
29-May-2018
No
No
International
Bordeaux Polymer Conference
28/05/2018 - 31/05/2018
Bordeaux
France
[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP)
[en] In light of recent efforts of applying principles of green and sustainable chemistry within macromolecular engineering, a large number of novel bio-sourced monomers are available. Especially cyclic carbonates (CCs), because of their effective ring-opening polymerisation to yield polymers such as non-isocyanate poly(urethane)s, has seen rapid progress during the past decade. Yet, very few examples exist of controlled radical polymerisations (CRP) of CCs bearing a double bond, part of the reason being that (i) up to now only some sustainable synthetic routes to such molecules are known and (ii) some interesting monomers contain an allylic-double bond that is challenging to control by most radical polymerization techniques. In this communication, we report on the synthesis of new bio-sourced polymers by the preparation of novel cyclic carbonate monomers from renewable resources followed by their controlled radical polymerization. Mainly bio-sourced allyl- or unconjugated vinyl-type cyclic carbonates are investigated. Cobalt-mediated radical polymerisation (CMRP) is used as a powerful CRP technique that is active for the polymerization of highly unreactive non-conjugated monomers under mild experimental conditions.
Complex and Entangled Systems from Atoms to Materials (CESAM) ; Center for Education and Research on Macromolecules (CERM)
THe EJD-Funmat project ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/224574
This flash oral communication was presented by Philip Scholten

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