No full text
Unpublished conference/Abstract (Scientific congresses and symposiums)
Controlled radical (co)polymerisation of allylic and vinylic monomers originating from renewable resources
Scholten, Philip; Demarteau, Jérémy; Gennen, Sandro et al.
2018The International Doctoral School in Functional Materials (EJD-FunMat) Training School
 

Files


Full Text
No document available.

Send to



Details



Keywords :
radical polymerization; cobalt-mediated radical polymerization (CMRP); supercritical carbon dioxide
Abstract :
[en] In light of recent efforts of applying principles of green and sustainable chemistry within macromolecular engineering, a large number of novel bio-sourced monomers are available. Especially cyclic carbonates (CCs), because of their effective polyaddition with polyamines to yield polymers such as non-isocyanate poly(urethane)s, have seen rapid progress during the past decade. Yet, very few examples exist of controlled radical polymerisations (CRP) of CCs bearing a double bond, part of the reason being that (i) up to now only some sustainable synthetic routes to such molecules are known and (ii) some interesting monomers contain reactive double bonds which are challenging to control by most radical polymerisation techniques. Herein we report on how cobalt-mediated radical polymerisation (CMRP) proves a powerful method for the (co)polymerisation of such monomers. Furthermore, the unique characteristics of the resulting (co)polymers and their value for applications in composites are highlighted.
Research center :
Center for Education and Research on Macromolecules (CERM)
CESAM - Complex and Entangled Systems from Atoms to Materials - ULiège
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Scholten, Philip ;  University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > Karlsruhe Institute of Technology (KIT), Institute of Organic Chemistry (IOC), Germany
Demarteau, Jérémy ;  University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Gennen, Sandro ;  University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
de Winter, Julien;  University of Mons, Organic Synthesis and Mass Spectrometry Laboratory, Belgium
Grignard, Bruno ;  University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine  ;  University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Meier, Michael A. R.;  Karlsruhe Institute of Technology (KIT), Institute of Organic Chemistry (IOC), Germany
Detrembleur, Christophe ;  University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Controlled radical (co)polymerisation of allylic and vinylic monomers originating from renewable resources
Publication date :
22 March 2018
Event name :
The International Doctoral School in Functional Materials (EJD-FunMat) Training School
Event place :
Luxembourg, Luxembourg
Event date :
18/03/2018 - 23/03/2018
Audience :
International
Funders :
The International Doctoral School EJF-Funmat
INEOS
Commentary :
This oral communication was presented by Filip Scholten
Available on ORBi :
since 17 April 2018

Statistics


Number of views
90 (2 by ULiège)
Number of downloads
0 (0 by ULiège)

Bibliography


Similar publications



Contact ORBi