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Investigation of the copolymerization behavior of a cyclic carbonate with vinyl acetate using CMRP
Scholten, Philip; Demarteau, Jérémy; Debuigne, Antoine et al.
2017International Doctoral School EJD-Funmat
 

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Keywords :
radical polymerization; cobalt-mediated radical polymerization (CMRP)
Abstract :
[en] Ethylene is an unconjugated monomer difficult to copolymerise in a controlled fashion using common radical or coordination-insertion polymerisation. Cobalt-mediated radical polymerisation (CMRP) provides a powerful means to radically copolymerise ethylene in a controlled fashion under mild conditions.[1][2] In addition, different copolymer structures, such as block or alternating, can be accessed. ACO2-based cyclic carbonate was chosen as a promising comonomer but conflicting reports on the copolymer structure have been reported.[3][4] To better understand the copolymerisation behaviour of this monomer, model copolymerisations with vinyl acetate were performed and are reported below with the aim of gaining insights into the copolymersiation behaviour, which will allow us to better tackle ethylene copolymerisations.
Research center :
Center for Education and Research on Macromolecules (CERM)
CESAM Complex and Entangled Systems from Atoms to Materials (CESAM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Scholten, Philip ;  University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Demarteau, Jérémy ;  University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine  ;  University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Grignard, Bruno ;  University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Meier, Michaël A. R.;  Karlsruhe Institute of Technology (KIT), Institute of Organic Chemistry (IOC), Germany
Detrembleur, Christophe ;  University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Investigation of the copolymerization behavior of a cyclic carbonate with vinyl acetate using CMRP
Publication date :
March 2017
Event name :
International Doctoral School EJD-Funmat
Event place :
Aveiro, Portugal
Event date :
26/03/2017 - 31/03/2017
Audience :
International
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
The International Doctoral School EJD-Funmat
Commentary :
This poster was presented by Philip Scholten
Available on ORBi :
since 01 June 2017

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