[en] Controlled radical polymerization techniques give access to innovative (multi)functional polymeric materials for advanced applications. Organometallic-mediated radical polymerization (OMRP) is one of these techniques that enable the preparation of unprecedented copolymers, and is based on the temporary deactivation of the propagating chains by a transition metal complex. The strength of the carbon-metal bond at the polymer chain-end is dictating the reactivity of the system. One of the most efficient OMRP process involves the commercially available Co(acac)2. Recent studies have demonstrated that the system reactivity is easily modulated by the addition of some molecules able to coordinate the cobalt complex, by tuning the temperature, or by UV irradiation. The facile modulation of the C-Co bond strength has enabled to control the polymerization of monomers of opposite reactivity, such as vinyl esters and acrylates, and to synthesize novel well-defined (co)polymers under very mild experimental conditions. In this talk, we will discuss some recent breakthroughs in the field that illustrate the huge potential of the process for the design of unique functional macromolecules. More precisely, we will describe the first control of the copolymerization of ethylene with a series of functional vinyl monomers under mild experimental conditions that leads to random copolymers with ethylene content up to 60 mol% and negligible chain branching. The first one-pot synthesis of novel ethylene-based block copolymers will also be discussed. Additionally, we will demonstrate the implementation of the OMRP process to aqueous based media by describing, amongst other examples, the precision synthesis of innovative functional (telechelic) poly(ionic liquid)s (PILs) in water.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Cordella, Daniela ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Demarteau, Jérémy ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Kermagoret, Anthony; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Patil, Nagaraj ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Organometallic-mediated radical polymerization, a versatile tool for the precision synthesis of unprecedented copolymers
Publication date :
17 December 2015
Event name :
Pacifichem
Event place :
Honolulu, United States - Hawaii
Event date :
15/12/2015 - 20/12/2015
By request :
Yes
Audience :
International
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique
Commentary :
This invited oral communication was presented by Christophe Detrembleur
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.