Publications of Grégoire Léonard
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See detailCapture, Utilisation et Stockage du CO2
Léonard, Grégoire ULiege

Scientific conference (2013, February)

Présentation des différentes techniques de capture du CO2, des principales voies de valorisation et de la technologie de stockage sous-terrain du CO2.

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See detailDynamic modelling and control of a pilot plant for post-combustion CO2 capture
Léonard, Grégoire ULiege; Cabeza Mogador, Bruno; Belletante, Ségolène et al

in Computer Aided Chemical Engineering (2013), 31

A dynamic model of a post-combustion pilot capture plant is developed using Aspen Plus Dynamics. An innovative process control strategy is studied for regulating the water balance of the process. A ... [more ▼]

A dynamic model of a post-combustion pilot capture plant is developed using Aspen Plus Dynamics. An innovative process control strategy is studied for regulating the water balance of the process. A washing section where the flue gas from the absorber is washed with cold water is included to the process in order to reduce the emissions of amine to the air. Control of the water balance in the solvent loop is successfully achieved by changing the washing water temperature. In previous publications regarding CO2 capture pilot plants, the regulation of the water balance always required a water make-up flow which appears here as unnecessary. Rejection of disturbances and different load reduction scenarios are tested to confirm the efficiency of this strategy. Potential operational problems of this control strategy are identified and solved. [less ▲]

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See detailModélisation du captage post-combustion du CO2 avec évaluation de la dégradation des solvants
Léonard, Grégoire ULiege; BELLETANTE, Ségolène; Cabeza Mogador, Bruno et al

in Récents Progrès en Génie des Procédés (2013), 104

Post-combustion CO2 capture in power plants is one of the most mature technologies for a short-term and large-scale decrease of CO2 emissions while simultaneously addressing the growing global energy ... [more ▼]

Post-combustion CO2 capture in power plants is one of the most mature technologies for a short-term and large-scale decrease of CO2 emissions while simultaneously addressing the growing global energy demand. CO2 is chemically absorbed in an amine solvent that can be regenerated at higher temperature, producing a pure CO2 stream. However, the large impact of this technology on the power plant efficiency and the environmental penalty are the main drawbacks for large-scale implementation. In this work, an innovative approach combining process modeling and evaluation of the environmental penalty due to amine degradation is presented. Based on experimental results, the kinetics of solvent oxidative and thermal degradation is estimated and included in the process model developed in Aspen Plus. Using this model, the influence of operating parameters like the oxygen concentration in the flue gas or the solvent regeneration pressure is studied. This model is a first step for a multi-objective optimization of the CO2 capture process, assessing both energy and environmental penalties of this technology. [less ▲]

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See detailProgress Report December 2012
Léonard, Grégoire ULiege

E-print/Working paper (2012)

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See detailLa capture du CO2: un défi pour l'avenir
Léonard, Grégoire ULiege

Scientific conference (2012, November)

General presentation of the CO2 capture technologies, the potential for CO2 valorization and the technology of CO2 storage. Presentation adressed to secondary school teachers.

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See detailCO2 CAPTURE in POWER PLANTS: Process Simulation and Solvent Degradation
Léonard, Grégoire ULiege; Lepaumier, Hélène; Thielens, Marie-Laure et al

Poster (2012, November)

Presentation of the research themes studied at the University of Liège in the field of CO2 capture

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See detailModélisation des grands systèmes chimiques: travaux pratiques
Gerkens, Carine; Leruth, Alexandre; Léonard, Grégoire ULiege et al

Learning material (2012)

Notes de Travaux pratiques à l'attention des étudiants 1ere master ingénieur civil chimiste et sciences des matériaux

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See detailProgress Report July 2012
Léonard, Grégoire ULiege

E-print/Working paper (2012)

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See detailDegradation inhibitors and metal additives: impact on solvent degradation
Léonard, Grégoire ULiege

Report (2012)

This report is part of a PhD thesis currently taking place at the University of Liège in collaboration with the company Laborelec. A Degradation Test Rig (DTR) has been built in order to evaluate solvent ... [more ▼]

This report is part of a PhD thesis currently taking place at the University of Liège in collaboration with the company Laborelec. A Degradation Test Rig (DTR) has been built in order to evaluate solvent degradation in CO2 capture conditions. Details about degradation effects and about the DTR may be found in a previous report (PhD mid-term report, G. Léonard, 2011). Experiments to study the effect of process conditions on degradation are in progress with 2-ethanolamine (MEA) as benchmark solvent. This report presents first a brief overview of the different degradation mechanisms and associated products, followed by a literature review about metal influence on MEA degradation and a state of the art review about degradation inhibitors. [less ▲]

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See detailPresentation of the report about degradation inhibitors and metal additives impact on solvent degradation
Léonard, Grégoire ULiege

Report (2012)

Literature review about impact of additives on solvent degradation

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See detailChimie et Science des Matériaux à l'Université de Liège
Léonard, Grégoire ULiege

Conference given outside the academic context (2012)

Présentation du métier d'ingénieur en chimie et science des matériaux à des étudiants de secondaire.

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See detailPOST-COMBUSTION CO2 CAPTURE: Global Process Simulation and Solvent Degradation
Léonard, Grégoire ULiege; Lepaumier, Hélène; Blandina, Fabrice et al

Poster (2012, February)

One of the biggest upcoming challenges concerning both environmental and energy systems engineering is the control and limitation of greenhouse gas emissions due to human activity. Fossil fuels-fired ... [more ▼]

One of the biggest upcoming challenges concerning both environmental and energy systems engineering is the control and limitation of greenhouse gas emissions due to human activity. Fossil fuels-fired power plants are in this context one of the main contributors due to the large amounts of CO2 emitted. Different technologies have been developed for capturing CO2 from such power plants. This work focuses on post-combustion CO2 capture by reactive absorption into amine solvents like monoethanolamine (MEA). The main drawback of this technology is actually the high energy requirement of the process, especially for solvent regeneration. It is then highly interesting to model the capture process so that optimal operating conditions could be approached by simulation thus reducing the number of expensive experimental tests. Thanks to the simulation, it has been possible to identify the most influent process variables and to optimize their value. It was also possible to study the impact of process modifications on the global capture efficiency. The improvements studied allowed for a reduction by up to 14% of the process exergy consumption. Another major drawback of the post-combustion CO2 capture is solvent degradation, which can be due to thermal as well as oxidative mechanisms. Degradation affects the CO2 capture process since it may cause corrosion, foaming and fouling, possibly inducing a decrease of the solvent efficiency and high additional operating costs due to solvent replacement. In order to study degradation of conventional amine solvents as well as degradation of novel solvents, a degradation test rig has been built at the University of Liège in collaboration with the company Laborelec, member of the GDF SUEZ group. First results show that degradation obtained on this lab installation can be compared to degradation results observed on CO2 capture pilot installation. The final objective of this thesis is to make a link between degradation and simulation. Experimental data obtained on the degradation test rig will be implemented into the existing simulation model so that optimal operating conditions considering both process energy efficiency and solvent degradation can be determined. [less ▲]

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See detailStudy of 2-Ethanolamine degradation
Léonard, Grégoire ULiege; Toye, Dominique ULiege; Heyen, Georges ULiege

Conference (2012, January)

One major drawback of the post-combustion CO2 capture using conventional amine solvents is solvent degradation, which can be due to thermal as well as oxidative mechanisms. Degradation affects the CO2 ... [more ▼]

One major drawback of the post-combustion CO2 capture using conventional amine solvents is solvent degradation, which can be due to thermal as well as oxidative mechanisms. Degradation affects the CO2 capture process since it may cause corrosion, foaming and fouling, possibly inducing a decrease of the solvent efficiency and high additional operating costs due to solvent replacement. In order to study degradation of conventional amine solvents as well as degradation of novel solvents, a degradation test rig has been built at the University of Liège in collaboration with the company Laborelec, member of the GDF SUEZ group. Since degradation generally occurs within a few months in real plant conditions, this equipment has been designed to allow the study of different degradation mechanisms under accelerated conditions, at high temperatures (up to 140°C) and high partial pressures in oxygen and CO2 (total pressure up to 20 bar with varying gas composition). An advantage of this degradation test rig is that it can be used in batch as well as in semi-batch mode with constant gas flow. High gas-liquid contact efficiency is also ensured thanks to a mechanical agitation system combined with gas bubbling. For a typical run, 300g of aqueous amine solution (30 wt % MEA in water) is introduced into the reactor and degraded during two weeks. The degraded solutions are then analysed using high pressure liquid chromatography (HPLC) for MEA quantification and gas chromatography with flame ionization detector (GC-FID) for the characterization of degradation products. The gas phase is analysed by Fourier Transform Infra Red spectroscopy. The final objective of this work is to implement the data obtained from experimental results on the degradation test rig into an existing simulation model that has been developed based on an existing pilot plant. [less ▲]

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See detailProgress Report December 2011
Léonard, Grégoire ULiege

E-print/Working paper (2011)

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See detailLa capture du CO2 en centrale électrique: Aperçu
Léonard, Grégoire ULiege

Learning material (2011)

Présentation dans le cadre des présentations d'options aux étudiants de 1ère bac

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See detailProgress Report August 2011
Léonard, Grégoire ULiege

E-print/Working paper (2011)

Présentation lors de la réunion de travail semestrielle avec Laborelec

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See detailMid-term report
Léonard, Grégoire ULiege

Report (2011)

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See detailModeling post-combustion CO2 capture with amine solvents
Léonard, Grégoire ULiege; Heyen, Georges ULiege

Poster (2011, June)

Carbon capture and storage is a technology that can contribute to face the challenge of rising energy demand combined with a growing environmental awareness. In the present work, the CO2 capture process ... [more ▼]

Carbon capture and storage is a technology that can contribute to face the challenge of rising energy demand combined with a growing environmental awareness. In the present work, the CO2 capture process with monoethanolamine (MEA) is modeled using the simulation tool Aspen Plus. Two different modeling approaches are studied and compared: the equilibrium and the rate-based approaches. An optimization of key process parameters is performed and process modifications are studied with the objective of improving the global process energy efficiency. [less ▲]

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See detailProgress Report April 2011
Léonard, Grégoire ULiege

E-print/Working paper (2011)

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See detailModeling post-combustion CO2 capture with amine solvents
Léonard, Grégoire ULiege; Heyen, Georges ULiege

in Computer Aided Chemical Engineering (2011), 29

Carbon capture and storage is a technology that can contribute to face the challenge of rising energy demand combined with a growing environmental awareness. In the present work, the CO2 capture process ... [more ▼]

Carbon capture and storage is a technology that can contribute to face the challenge of rising energy demand combined with a growing environmental awareness. In the present work, the CO2 capture process with monoethanolamine (MEA) is modeled using the simulation tool Aspen Plus. Two different modeling approaches are studied and compared: the equilibrium and the rate-based approaches. An optimization of key process parameters is performed and process modifications are studied with the objective of improving the global process energy efficiency. [less ▲]

Detailed reference viewed: 187 (46 ULiège)