Publications and communications of Bruno Grignard

Articles in scientific journals with peer reviewing

Muzyka, C., Renson, S., Grignard, B., Detrembleur, C., & Monbaliu, J.-C. (2024). Intensified Continuous Flow Process for the Scalable Production of Bio-Based Glycerol Carbonate. Angewandte Chemie International Edition, 202319060. doi:10.1002/anie.202319060

Habets, T., Olmedo-Martínez, J. L., Del Olmo, R., Grignard, B., Mecerreyes, D., & Detrembleur, C. (21 July 2023). Facile access to CO2-sourced polythiocarbonate dynamic networks and their potential as solid-state electrolytes for lithium metal batteries. ChemSusChem, 16 (14), 202300225. doi:10.1002/cssc.202300225

Seychal, G., Ocando, C., Bonnaud, L., De Winter, J., Grignard, B., Detrembleur, C., Sardon, H., Aramburu, N., & Raquez, J.-M. (14 July 2023). Emerging polyhydroxyurethanes as sustainable thermosets: a structure–property relationship. ACS Applied Polymer Materials, 5 (7), 5567 - 5581. doi:10.1021/acsapm.3c00879

Delma, K. L., Penoy, N., Sakira, A. K., EGREK, S., Sacheli, R., Grignard, B., Hayette, M.-P., Issa Somé, T., Evrard, B., Semdé, R., & Piel, G. (11 January 2023). Use of supercritical CO2 for the sterilization of liposomes: Study of the influence of sterilization conditions on the chemical and physical stability of phospholipids and liposomes. European Journal of Pharmaceutics and Biopharmaceutics, 183, 112 - 118. doi:10.1016/j.ejpb.2023.01.002

Bourguignon, M., Grignard, B., & Detrembleur, C. (19 December 2022). Water‐induced self‐blown non‐isocyanate polyurethane foams. Angewandte Chemie International Edition, 61 (51), 202213422. doi:10.1002/anie.202213422

Grignard, B., Mampuys, P., Escudero, J., Masullo, D., Lemière, F., Maes, B. U. W., & Detrembleur, C. (08 November 2022). Functional regioregular (poly)urethanes from soft nucleophiles and cyclic iminocarbonates. Polymer Chemistry, 13 (48), 6599 - 6605. doi:10.1039/d2py01077a

Habets, T., Siragusa, F., Müller, A. J., Grossman, Q., Ruffoni, D., Grignard, B., & Detrembleur, C. (07 June 2022). Facile construction of functional poly(monothiocarbonate) copolymers under mild operating conditions. Polymer Chemistry, 13 (21), 3076-3090. doi:10.1039/d2py00307d

Li, X., Villar-Yanez, A., Ngassam Tounzoua, C., Benet-Buchholz, J., Grignard, B., Bo, C., Detrembleur, C., & Kleij, A. W. (15 February 2022). Cascade transformation of carbon dioxide and alkyne-1,n-diols into densely substituted cyclic carbonates. ACS Catalysis, 12 (5), 2854-2860. doi:10.1021/acscatal.1c05773

Monie, F.* , Grignard, B.* , & Detrembleur, C.*. (15 February 2022). Divergent aminolysis approach for constructing recyclable self-blown nonisocyanate polyurethane foams. ACS Macro Letters, 11 (2), 236-242. doi:10.1021/acsmacrolett.1c00793
* These authors have contributed equally to this work.

Brege, A., Grignard, B., Méreau, R., Detrembleur, C., Jérôme, C., & Tassaing, T. (20 January 2022). En route to CO2-based (a)cyclic carbonates and polycarbonates from alcohols substrates by direct and indirect approaches. Catalysts, 12 (2), 124. doi:10.3390/catal12020124

Gomez-Lopez, A., Ayensa, N., Grignard, B., Irusta, L., Iñigo, C., Müller, A. J., Detrembleur, C., & Sardon, H. (10 January 2022). Enhanced and reusable poly(hydroxy urethane)-based low temperature hot-melt adhesives. ACS Applied Polymer Materials, 2 (3), 194.207. doi:10.1021/acspolymersau.1c00053

Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (08 May 2018). Merging CO2‑based building blocks with cobalt-mediated radical polymerization for the synthesis of functional poly(vinyl alcohol)s. Macromolecules, 51 (9), 3379-3393. doi:10.1021/acs.macromol.8b00492

Alves, M., Grignard, B., Gennen, S., Detrembleur, C., Jérôme, C., & Tassaing, T. (2015). Organocatalytic synthesis of bio-based cyclic carbonates from CO2 and vegetable oils. RSC Advances, 5, 53629-53636. doi:10.1039/C5RA10190E

Grignard, B., Schmeits, S., Riva, R., Detrembleur, C., Lecomte, P., & Jérôme, C. (November 2009). First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters. Green Chemistry, 11, 1525-1529. doi:10.1039/b822924d

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (March 2008). Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide. European Polymer Journal, 44 (3), 861-871. doi:10.1016/j.eurpolymj.2007.11.020

Grignard, B., Calberg, C., Jérôme, C., Wang, W., Howdle, S., & Detrembleur, C. (2008). Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues. Chemical Communications, (44), 5803-5805. doi:10.1039/b812297k


Detrembleur, C., Grignard, B., & Bourguignon, M. (15 June 2023). Self-blowing isocyanate-free polyurethane foams.

Scientific conferences in universities or research centers

Léonard, G., Toye, D., & Grignard, B. (January 2016). Reactors for CO2 utilization [Paper presentation]. Visit to the University of Edinburgh.

Scientific congresses and symposiums

Oral communications or posters

Penoy, N., Delma, K. L., Grignard, B., Evrard, B., & Piel, G. (23 May 2023). The use of supercritical CO2 to develop liposomes encapsulating active pharmaceutical ingredients for pulmonary administration [Poster presentation]. 19th European Meeting on Supercritical Fluids, Budapest, Hungary.

Penoy, N., Grignard, B., Evrard, B., & Piel, G. (06 April 2021). Double Encapsulation in liposomes for pulmonary administration produced by an innovative supercritical process [Paper presentation]. Controlled Release Society BeNeLux&France Early Career Scientists Meeting (online).

Penoy, N., Koch, N., Grignard, B., Evrard, B., & Piel, G. (March 2021). The quality by design strategy to prepare different liposomes formulations by a new supercritical fluid method [Poster presentation]. APGI Meeting on Pharmaceutics, Biopharmaceutics and Pharmaceutical Technology.

Léonard, G., Belet, A., Grignard, B. (Other coll.), Calberg, C. (Other coll.), Gilbert, B. (Other coll.), & Heinrichs, B. (Other coll.). (09 July 2018). HETEROGENIZATION OF A CYCLOCARBONATION CATALYST [Poster presentation]. 12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts", Louvain-La-Neuve, Belgium.

Alaimo, D., Beigbeder, A., Dubois, P., Broze, G., Grignard, B., & Jérôme, C. (29 November 2010). New fluorinated surfactants for nanogels preparation in supercritical CO2 [Poster presentation]. PAI P6/27 Annual Meeting, Brussels, Belgium.

Riva, R., Schmeits, S., Croisier, F., Lussis, P., Grignard, B., Lecomte, P., & Jérôme, C. (13 July 2010). Contribution of "click chemistry" to the macromolecular engineering of aliphatic polyesters [Poster presentation]. MACRO 2010, 43rde IUPAC World Polymer Congress, Polymer Science in the Service of Society, Glasgow, United Kingdom.

Grignard, B., Schmeits, S., Riva, R., Lecomte, P., Detrembleur, C., & Jérôme, C. (16 November 2009). Functional aliphatic polyesters by click chemistry in supercritical carbon dioxide [Paper presentation]. Workshop on Supercritical Fluids Processing of Biopolymers and Biomedical Materials, Funchal (Madeira), Portugal.

Lecomte, P., Riva, R., Schmeits, S., Croisier, F., Grignard, B., Jérôme, R., & Jérôme, C. (03 June 2009). New developments in the functionalization of aliphatic polyesters by "click" copper-catalyzed azide-alkyne cycloaddition [Paper presentation]. EUPOC2009, EPF Europolymer Conference, "Click" - Methods in Polymer and Materials Science, Gargnano, Italy.

Grignard, B., Schmeits, S., Riva, R., Lecomte, P., Detrembleur, C., & Jérôme, C. (19 May 2009). Click reaction in supercritical carbon dioxide: towards the synthesis of functional polymers in a green medium [Paper presentation]. 9th International Symposium on Supercritical Fluids (ISSF 2009) : New Trends in Supercritical Fluids ; Energy, Materials, Processing, Arcachon, France.

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (28 November 2008). Design of perfluorinated macroligand for the implementation of atom transfer radical polymerization in supercritical carbon dioxide [Paper presentation]. PAI P6/27 Annual Meeting, Leuven, Belgium.

Grignard, B., Urbanczyk, L., Stassin, F., Calberg, C., Detrembleur, C., & Jérôme, C. (02 June 2008). Supercritical carbon dioxide, a tool for the dispersion ROP of lactone and PCL foaming: Part A [Poster presentation]. Workshop on biomacromolecules, Renewable, Degradable and Biomedical Polymers, Stockholm, Sweden.

Grignard, B., Vaillant, A., De Coninck, J., & Jérôme, C. (22 May 2008). Superhydrophobic surfaces by electrospinning of polymer mixtures [Poster presentation]. Belgian Polymer Group (BPG) annual meeting 2008, De Haan, Belgium.

Other publications and communications

Articles in scientific journals without peer reviewing

Grignard, B. (2019). Le CO2, un déchet au service de l'innovation. Bulletin de la Société Royale des Sciences de Liège, 88, 64 - 72. doi:10.25518/0037-9565.9205