Delcorps, J., Rawat, K. S., Wells, M., Ben Ayed, E., Grignard, B., Detrembleur, C., Blankert, B., Gerbaux, P., Van Speybroeck, V., & Coulembier, O. (2024). Turning carbon dioxide into dialkyl carbonates through guanidinium-assisted SN2 ion-pair process. Cell Reports. Physical Science, 102057. doi:10.1016/j.xcrp.2024.102057 |
Penoy, N.* , Delma, K. L.* , Homkar, N., Karim Sakira, A., Egrek, S., Sacheli, R., Sacre, P.-Y., Grignard, B., Hayette, M.-P., Somé, T. I., Semdé, R., Evrard, B., & Piel, G. (15 February 2024). Development and optimization of a one step process for the production and sterilization of liposomes using supercritical CO2. International Journal of Pharmaceutics, 651, 123769. doi:10.1016/j.ijpharm.2024.123769 * These authors have contributed equally to this work. |
Muzyka, C., Renson, S., Grignard, B., Detrembleur, C., & Monbaliu, J.-C. (2024). Intensified Continuous Flow Process for the Scalable Production of Bio-Based Glycerol Carbonate. Angewandte Chemie International Edition, 202319060. doi:10.1002/anie.202319060 |
Habets, T., Seychal, G., Caliari, M., Raquez, J.-M., Sardon, H., Grignard, B., & Detrembleur, C. (22 November 2023). Covalent Adaptable Networks through Dynamic N,S-Acetal Chemistry: Toward Recyclable CO2-Based Thermosets. Journal of the American Chemical Society, 145 (46), 25450 - 25462. doi:10.1021/jacs.3c10080 |
Habets, T., Olmedo-Martínez, J. L., Del Olmo, R., Grignard, B., Mecerreyes, D., & Detrembleur, C. (21 July 2023). Facile access to CO2-sourced polythiocarbonate dynamic networks and their potential as solid-state electrolytes for lithium metal batteries. ChemSusChem, 16 (14), 202300225. doi:10.1002/cssc.202300225 |
Seychal, G., Ocando, C., Bonnaud, L., De Winter, J., Grignard, B., Detrembleur, C., Sardon, H., Aramburu, N., & Raquez, J.-M. (14 July 2023). Emerging polyhydroxyurethanes as sustainable thermosets: a structure–property relationship. ACS Applied Polymer Materials, 5 (7), 5567 - 5581. doi:10.1021/acsapm.3c00879 |
Siragusa, F., Detrembleur, C., & Grignard, B. (21 March 2023). The advent of recyclable CO2-based polycarbonates. Polymer Chemistry, 10 (27), 8863-8875. doi:10.1039/d2py01258h |
Delma, K. L., Penoy, N., Sakira, A. K., EGREK, S., Sacheli, R., Grignard, B., Hayette, M.-P., Issa Somé, T., Evrard, B., Semdé, R., & Piel, G. (11 January 2023). Use of supercritical CO2 for the sterilization of liposomes: Study of the influence of sterilization conditions on the chemical and physical stability of phospholipids and liposomes. European Journal of Pharmaceutics and Biopharmaceutics, 183, 112 - 118. doi:10.1016/j.ejpb.2023.01.002 |
Bourguignon, M., Grignard, B., & Detrembleur, C. (19 December 2022). Water‐induced self‐blown non‐isocyanate polyurethane foams. Angewandte Chemie International Edition, 61 (51), 202213422. doi:10.1002/anie.202213422 |
Grignard, B., Mampuys, P., Escudero, J., Masullo, D., Lemière, F., Maes, B. U. W., & Detrembleur, C. (08 November 2022). Functional regioregular (poly)urethanes from soft nucleophiles and cyclic iminocarbonates. Polymer Chemistry, 13 (48), 6599 - 6605. doi:10.1039/d2py01077a |
Habets, T., Siragusa, F., Müller, A. J., Grossman, Q., Ruffoni, D., Grignard, B., & Detrembleur, C. (07 June 2022). Facile construction of functional poly(monothiocarbonate) copolymers under mild operating conditions. Polymer Chemistry, 13 (21), 3076-3090. doi:10.1039/d2py00307d |
Li, X., Villar-Yanez, A., Ngassam Tounzoua, C., Benet-Buchholz, J., Grignard, B., Bo, C., Detrembleur, C., & Kleij, A. W. (15 February 2022). Cascade transformation of carbon dioxide and alkyne-1,n-diols into densely substituted cyclic carbonates. ACS Catalysis, 12 (5), 2854-2860. doi:10.1021/acscatal.1c05773 |
Monie, F.* , Grignard, B.* , & Detrembleur, C.*. (15 February 2022). Divergent aminolysis approach for constructing recyclable self-blown nonisocyanate polyurethane foams. ACS Macro Letters, 11 (2), 236-242. doi:10.1021/acsmacrolett.1c00793 * These authors have contributed equally to this work. |
Brege, A., Grignard, B., Méreau, R., Detrembleur, C., Jérôme, C., & Tassaing, T. (20 January 2022). En route to CO2-based (a)cyclic carbonates and polycarbonates from alcohols substrates by direct and indirect approaches. Catalysts, 12 (2), 124. doi:10.3390/catal12020124 |
Gomez-Lopez, A., Ayensa, N., Grignard, B., Irusta, L., Iñigo, C., Müller, A. J., Detrembleur, C., & Sardon, H. (10 January 2022). Enhanced and reusable poly(hydroxy urethane)-based low temperature hot-melt adhesives. ACS Applied Polymer Materials, 2 (3), 194.207. doi:10.1021/acspolymersau.1c00053 |
Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (08 May 2018). Merging CO2‑based building blocks with cobalt-mediated radical polymerization for the synthesis of functional poly(vinyl alcohol)s. Macromolecules, 51 (9), 3379-3393. doi:10.1021/acs.macromol.8b00492 |
Alves, M., Grignard, B., Gennen, S., Detrembleur, C., Jérôme, C., & Tassaing, T. (2015). Organocatalytic synthesis of bio-based cyclic carbonates from CO2 and vegetable oils. RSC Advances, 5, 53629-53636. doi:10.1039/C5RA10190E |
Grignard, B., Schmeits, S., Riva, R., Detrembleur, C., Lecomte, P., & Jérôme, C. (November 2009). First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters. Green Chemistry, 11, 1525-1529. doi:10.1039/b822924d |
Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (March 2008). Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide. European Polymer Journal, 44 (3), 861-871. doi:10.1016/j.eurpolymj.2007.11.020 |
Grignard, B., Calberg, C., Jérôme, C., Wang, W., Howdle, S., & Detrembleur, C. (2008). Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues. Chemical Communications, (44), 5803-5805. doi:10.1039/b812297k |
Detrembleur, C., Grignard, B., & Bourguignon, M. (15 June 2023). Self-blowing isocyanate-free polyurethane foams. |
Léonard, G., Toye, D., & Grignard, B. (January 2016). Reactors for CO2 utilization [Paper presentation]. Visit to the University of Edinburgh. |
Penoy, N., Delma, K. L., Grignard, B., Evrard, B., & Piel, G. (23 May 2023). The use of supercritical CO2 to develop liposomes encapsulating active pharmaceutical ingredients for pulmonary administration [Poster presentation]. 19th European Meeting on Supercritical Fluids, Budapest, Hungary. |
Penoy, N., Grignard, B., Evrard, B., & Piel, G. (06 April 2021). Double Encapsulation in liposomes for pulmonary administration produced by an innovative supercritical process [Paper presentation]. Controlled Release Society BeNeLux&France Early Career Scientists Meeting (online). |
Penoy, N., Koch, N., Grignard, B., Evrard, B., & Piel, G. (March 2021). The quality by design strategy to prepare different liposomes formulations by a new supercritical fluid method [Poster presentation]. APGI Meeting on Pharmaceutics, Biopharmaceutics and Pharmaceutical Technology. |
Léonard, G., Belet, A., Grignard, B. (Other coll.), Calberg, C. (Other coll.), Gilbert, B. (Other coll.), & Heinrichs, B. (Other coll.). (09 July 2018). HETEROGENIZATION OF A CYCLOCARBONATION CATALYST [Poster presentation]. 12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts", Louvain-La-Neuve, Belgium. |
Alaimo, D., Beigbeder, A., Dubois, P., Broze, G., Grignard, B., & Jérôme, C. (29 November 2010). New fluorinated surfactants for nanogels preparation in supercritical CO2 [Poster presentation]. PAI P6/27 Annual Meeting, Brussels, Belgium. |
Riva, R., Schmeits, S., Croisier, F., Lussis, P., Grignard, B., Lecomte, P., & Jérôme, C. (13 July 2010). Contribution of "click chemistry" to the macromolecular engineering of aliphatic polyesters [Poster presentation]. MACRO 2010, 43rde IUPAC World Polymer Congress, Polymer Science in the Service of Society, Glasgow, United Kingdom. |
Grignard, B., Schmeits, S., Riva, R., Lecomte, P., Detrembleur, C., & Jérôme, C. (16 November 2009). Functional aliphatic polyesters by click chemistry in supercritical carbon dioxide [Paper presentation]. Workshop on Supercritical Fluids Processing of Biopolymers and Biomedical Materials, Funchal (Madeira), Portugal. |
Lecomte, P., Riva, R., Schmeits, S., Croisier, F., Grignard, B., Jérôme, R., & Jérôme, C. (03 June 2009). New developments in the functionalization of aliphatic polyesters by "click" copper-catalyzed azide-alkyne cycloaddition [Paper presentation]. EUPOC2009, EPF Europolymer Conference, "Click" - Methods in Polymer and Materials Science, Gargnano, Italy. |
Grignard, B., Schmeits, S., Riva, R., Lecomte, P., Detrembleur, C., & Jérôme, C. (19 May 2009). Click reaction in supercritical carbon dioxide: towards the synthesis of functional polymers in a green medium [Paper presentation]. 9th International Symposium on Supercritical Fluids (ISSF 2009) : New Trends in Supercritical Fluids ; Energy, Materials, Processing, Arcachon, France. |
Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (28 November 2008). Design of perfluorinated macroligand for the implementation of atom transfer radical polymerization in supercritical carbon dioxide [Paper presentation]. PAI P6/27 Annual Meeting, Leuven, Belgium. |
Grignard, B., Urbanczyk, L., Stassin, F., Calberg, C., Detrembleur, C., & Jérôme, C. (02 June 2008). Supercritical carbon dioxide, a tool for the dispersion ROP of lactone and PCL foaming: Part A [Poster presentation]. Workshop on biomacromolecules, Renewable, Degradable and Biomedical Polymers, Stockholm, Sweden. |
Grignard, B., Vaillant, A., De Coninck, J., & Jérôme, C. (22 May 2008). Superhydrophobic surfaces by electrospinning of polymer mixtures [Poster presentation]. Belgian Polymer Group (BPG) annual meeting 2008, De Haan, Belgium. |
Grignard, B. (2019). Le CO2, un déchet au service de l'innovation. Bulletin de la Société Royale des Sciences de Liège, 88, 64 - 72. doi:10.25518/0037-9565.9205 |