Publications and communications of Bruno Grignard

Seychal, G., Ximenis, M., Lemaur, V., Grignard, B., Lazzaroni, R., Detrembleur, C., Sardon, H., Aranburu, N., & Raquez, J. M. (09 January 2025). Synergetic hybridization strategy to enhance the dynamicity of poorly dynamic CO2‐derived vitrimers achieved by a simple copolymerization approach. Advanced Functional Materials, 35 (2), 2412268. doi:10.1002/adfm.202412268

Abbasoglu, T., Skarsetz, O., Fanlo, P., Grignard, B., Detrembleur, C., Walther, A., & Sardon, H. (2024). Spatio‐selective reconfiguration of mechanical metamaterials through the use of dynamic covalent chemistries. Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2407746. doi:10.1002/advs.202407746

Habets, T., Méreau, R., Siragusa, F., Grignard, B., & Detrembleur, C. (19 November 2024). Fast, Regioselective Aminolysis of Tetrasubstituted Cyclic Carbonates and Application to Recyclable Thermoplastics and Thermosets. ACS Macro Letters, 13, 1425-1432. doi:10.1021/acsmacrolett.4c00570

Seychal, G., Nickmilder, P., Lemaur, V., Ocando, C., Grignard, B., Leclère, P., Detrembleur, C., Lazzaroni, R., Sardon, H., Aranburu, N., & Raquez, J.-M. (October 2024). A novel approach to design structural natural fiber composites from sustainable CO2-derived polyhydroxyurethane thermosets with outstanding properties and circular features. Composites. Part A, Applied Science and Manufacturing, 185, 108311. doi:10.1016/j.compositesa.2024.108311

Trojanowska, D., Monie, F., Perotto, G., Athanassiou, A., Grignard, B., Grau, E., Vidil, T., Cramail, H., & Detrembleur, C. (21 July 2024). Valorization of waste biomass for the fabrication of isocyanate-free polyurethane foams. Green Chemistry, 26 (14), 8383-8394. doi:10.1039/d4gc01547a

Delcorps, J., Rawat, K. S., Wells, M., Ben Ayed, E., Grignard, B., Detrembleur, C., Blankert, B., Gerbaux, P., Van Speybroeck, V., & Coulembier, O. (2024). Turning carbon dioxide into dialkyl carbonates through guanidinium-assisted SN2 ion-pair process. Cell Reports. Physical Science, 102057. doi:10.1016/j.xcrp.2024.102057

Razavi-Esfali, M., Habets, T., Siragusa, F., Grignard, B., Sardon, H., & Detrembleur, C. (21 May 2024). Design of functional isocyanate-free poly(oxazolidone)s under mild conditions. Polymer Chemistry, 15 (19), 1962-1974. doi:10.1039/d4py00101j

Maes, S.* , Habets, T.* , Fischer, S. M., Grignard, B., Detrembleur, C.* , & Du Prez, F. E.*. (10 May 2024). Unprecedented associative exchange in CO2-sourced cyclic S,O-acetal-based covalent adaptable networks. Polymer Chemistry, 15 (22), 2296 - 2307. doi:10.1039/d4py00359d

Penoy, N.* , Delma, K. L.* , Homkar, N., Karim Sakira, A., Egrek, S., Sacheli, R., Sacre, P.-Y., Grignard, B., Hayette, M.-P., Somé, T. I., Semdé, R., Evrard, B., & Piel, G. (15 February 2024). Development and optimization of a one step process for the production and sterilization of liposomes using supercritical CO2. International Journal of Pharmaceutics, 651, 123769. doi:10.1016/j.ijpharm.2024.123769

Muzyka, C., Renson, S., Grignard, B., Detrembleur, C., & Monbaliu, J.-C. (2024). Intensified Continuous Flow Process for the Scalable Production of Bio-Based Glycerol Carbonate. Angewandte Chemie International Edition, 202319060. doi:10.1002/anie.202319060

Habets, T., Seychal, G., Caliari, M., Raquez, J.-M., Sardon, H., Grignard, B., & Detrembleur, C. (22 November 2023). Covalent Adaptable Networks through Dynamic N,S-Acetal Chemistry: Toward Recyclable CO2-Based Thermosets. Journal of the American Chemical Society, 145 (46), 25450 - 25462. doi:10.1021/jacs.3c10080

Habets, T., Olmedo-Martínez, J. L., Del Olmo, R., Grignard, B., Mecerreyes, D., & Detrembleur, C. (21 July 2023). Facile access to CO2-sourced polythiocarbonate dynamic networks and their potential as solid-state electrolytes for lithium metal batteries. ChemSusChem, 16 (14), 202300225. doi:10.1002/cssc.202300225

Seychal, G., Ocando, C., Bonnaud, L., De Winter, J., Grignard, B., Detrembleur, C., Sardon, H., Aramburu, N., & Raquez, J.-M. (14 July 2023). Emerging polyhydroxyurethanes as sustainable thermosets: a structure–property relationship. ACS Applied Polymer Materials, 5 (7), 5567 - 5581. doi:10.1021/acsapm.3c00879

Siragusa, F., Detrembleur, C., & Grignard, B. (21 March 2023). The advent of recyclable CO2-based polycarbonates. Polymer Chemistry, 10 (27), 8863-8875. doi:10.1039/d2py01258h

Delma, K. L., Penoy, N., Sakira, A. K., EGREK, S., Sacheli, R., Grignard, B., Hayette, M.-P., Issa Somé, T., Evrard, B., Semdé, R., & Piel, G. (11 January 2023). Use of supercritical CO2 for the sterilization of liposomes: Study of the influence of sterilization conditions on the chemical and physical stability of phospholipids and liposomes. European Journal of Pharmaceutics and Biopharmaceutics, 183, 112 - 118. doi:10.1016/j.ejpb.2023.01.002

Bourguignon, M., Grignard, B., & Detrembleur, C. (19 December 2022). Water‐induced self‐blown non‐isocyanate polyurethane foams. Angewandte Chemie International Edition, 61 (51), 202213422. doi:10.1002/anie.202213422

Grignard, B., Mampuys, P., Escudero, J., Masullo, D., Lemière, F., Maes, B. U. W., & Detrembleur, C. (08 November 2022). Functional regioregular (poly)urethanes from soft nucleophiles and cyclic iminocarbonates. Polymer Chemistry, 13 (48), 6599 - 6605. doi:10.1039/d2py01077a

Habets, T., Siragusa, F., Müller, A. J., Grossman, Q., Ruffoni, D., Grignard, B., & Detrembleur, C. (07 June 2022). Facile construction of functional poly(monothiocarbonate) copolymers under mild operating conditions. Polymer Chemistry, 13 (21), 3076-3090. doi:10.1039/d2py00307d

Li, X., Villar-Yanez, A., Ngassam Tounzoua, C., Benet-Buchholz, J., Grignard, B., Bo, C., Detrembleur, C., & Kleij, A. W. (15 February 2022). Cascade transformation of carbon dioxide and alkyne-1,n-diols into densely substituted cyclic carbonates. ACS Catalysis, 12 (5), 2854-2860. doi:10.1021/acscatal.1c05773

Monie, F.* , Grignard, B.* , & Detrembleur, C.*. (15 February 2022). Divergent aminolysis approach for constructing recyclable self-blown nonisocyanate polyurethane foams. ACS Macro Letters, 11 (2), 236-242. doi:10.1021/acsmacrolett.1c00793

Brege, A., Grignard, B., Méreau, R., Detrembleur, C., Jérôme, C., & Tassaing, T. (20 January 2022). En route to CO2-based (a)cyclic carbonates and polycarbonates from alcohols substrates by direct and indirect approaches. Catalysts, 12 (2), 124. doi:10.3390/catal12020124

Gomez-Lopez, A., Ayensa, N., Grignard, B., Irusta, L., Iñigo, C., Müller, A. J., Detrembleur, C., & Sardon, H. (10 January 2022). Enhanced and reusable poly(hydroxy urethane)-based low temperature hot-melt adhesives. ACS Applied Polymer Materials, 2 (3), 194.207. doi:10.1021/acspolymersau.1c00053

Gomez-Lopez, A., Grignard, B., Calvo, I., Detrembleur, C., & Sardon, H. (2022). Accelerating the Curing of Hybrid Poly(Hydroxy Urethane)-Epoxy Adhesives by the Thiol-Epoxy Chemistry. ACS Applied Polymer Materials, 4 (12), 8786-8794. doi:10.1021/acsapm.2c01195

Gomez-Lopez, A., Panchireddy, S., Grignard, B., Calvo, I., Jérôme, C., Detrembleur, C., & Sardon, H. (26 July 2021). Poly(hydroxyurethane) adhesives and coatings: state-of-the-art and future directions. ACS Sustainable Chemistry and Engineering, 9 (28), 9541-9562. doi:10.1021/acssuschemeng.1c02558

Habets, T., Siragusa, F., Grignard, B., & Detrembleur, C. (11 August 2020). Advancing the synthesis of isocyanate-free poly(oxazolidones)s: scope and limitations. Macromolecules, 53 (15), 6393-6408. doi:10.1021/acs.macromol.0c01231

Brege, A., Méreau, R., McGehee, K., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (May 2020). The coupling of CO2 with diols promoted by organic dual systems: Towards products divergence via benchmarking of the performance metrics. Journal of CO2 Utilization, 38, 88-98. doi:10.1016/j.jcou.2020.01.003

Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (08 May 2018). Merging CO2‑based building blocks with cobalt-mediated radical polymerization for the synthesis of functional poly(vinyl alcohol)s. Macromolecules, 51 (9), 3379-3393. doi:10.1021/acs.macromol.8b00492

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (31 March 2017). DFT investigation of the reaction mechanism for the guanidine catalyzed ring-opening of cyclic carbonates by aromatic and alkyl-amines. RSC Advances, 7 (31), 18993-19001. doi:10.1039/c7ra00220c

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (2016). A comprehensive density functional theory study of the key role of fluorination and dual hydrogen bonding in the activation of the epoxide/CO2 coupling by fluorinated alcohols. RSC Advances, 6 (43), 36327-36335. doi:10.1039/C6RA03427F

Galia, A., Scialdone, O., Spanò, T., Valenti, M. G., Grignard, B., Lecomte, P., Monflier, E., Tilloy, S., & Rousseau, C. (2016). Ring opening polymerization of ε-caprolactone in the presence of wet β-cyclodextrin: effect of the operative pressure and of water molecules in the β-cyclodextrin cavity. RSC Advances, 6, 90290-90299. doi:10.1039/C6RA20211J

Alves, M., Grignard, B., Gennen, S., Detrembleur, C., Jérôme, C., & Tassaing, T. (2015). Organocatalytic synthesis of bio-based cyclic carbonates from CO2 and vegetable oils. RSC Advances, 5, 53629-53636. doi:10.1039/C5RA10190E

Grignard, B., Schmeits, S., Riva, R., Detrembleur, C., Lecomte, P., & Jérôme, C. (November 2009). First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters. Green Chemistry, 11, 1525-1529. doi:10.1039/b822924d

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (March 2008). Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide. European Polymer Journal, 44 (3), 861-871. doi:10.1016/j.eurpolymj.2007.11.020

Grignard, B., Calberg, C., Jérôme, C., Wang, W., Howdle, S., & Detrembleur, C. (2008). Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues. Chemical Communications, (44), 5803-5805. doi:10.1039/b812297k

Detrembleur, C., Grignard, B., & Monie, F. (December 2023). Self-blowing isocyanate-free polyurethane foams.

Detrembleur, C., Grignard, B., & Bourguignon, M. (15 June 2023). Self-blowing isocyanate-free polyurethane foams.

Léonard, G., Toye, D., & Grignard, B. (January 2016). Reactors for CO2 utilization [Paper presentation]. Visit to the University of Edinburgh.