Publications and communications of Bruno Grignard

Articles in scientific journals with peer reviewing

Muzyka, C., Renson, S., Grignard, B., Detrembleur, C., & Monbaliu, J.-C. (2024). Intensified Continuous Flow Process for the Scalable Production of Bio-Based Glycerol Carbonate. Angewandte Chemie International Edition, 202319060. doi:10.1002/anie.202319060

Bourguignon, M., Grignard, B., & Detrembleur, C. (2024). Cascade Exotherms for Rapidly Producing Hybrid Nonisocyanate Polyurethane Foams from Room Temperature Formulations. Journal of the American Chemical Society. doi:10.1021/jacs.3c11637

Habets, T., Seychal, G., Caliari, M., Raquez, J.-M., Sardon, H., Grignard, B., & Detrembleur, C. (22 November 2023). Covalent Adaptable Networks through Dynamic N,S-Acetal Chemistry: Toward Recyclable CO2-Based Thermosets. Journal of the American Chemical Society, 145 (46), 25450 - 25462. doi:10.1021/jacs.3c10080

Habets, T., Olmedo-Martínez, J. L., Del Olmo, R., Grignard, B., Mecerreyes, D., & Detrembleur, C. (21 July 2023). Facile access to CO2-sourced polythiocarbonate dynamic networks and their potential as solid-state electrolytes for lithium metal batteries. ChemSusChem, 16 (14), 202300225. doi:10.1002/cssc.202300225

Seychal, G., Ocando, C., Bonnaud, L., De Winter, J., Grignard, B., Detrembleur, C., Sardon, H., Aramburu, N., & Raquez, J.-M. (14 July 2023). Emerging polyhydroxyurethanes as sustainable thermosets: a structure–property relationship. ACS Applied Polymer Materials, 5 (7), 5567 - 5581. doi:10.1021/acsapm.3c00879

Siragusa, F., Detrembleur, C., & Grignard, B. (21 March 2023). The advent of recyclable CO2-based polycarbonates. Polymer Chemistry, 10 (27), 8863-8875. doi:10.1039/d2py01258h

Delma, K. L., Penoy, N., Sakira, A. K., EGREK, S., Sacheli, R., Grignard, B., Hayette, M.-P., Issa Somé, T., Evrard, B., Semdé, R., & Piel, G. (11 January 2023). Use of supercritical CO2 for the sterilization of liposomes: Study of the influence of sterilization conditions on the chemical and physical stability of phospholipids and liposomes. European Journal of Pharmaceutics and Biopharmaceutics, 183, 112 - 118. doi:10.1016/j.ejpb.2023.01.002

Bourguignon, M., Grignard, B., & Detrembleur, C. (19 December 2022). Water‐induced self‐blown non‐isocyanate polyurethane foams. Angewandte Chemie International Edition, 61 (51), 202213422. doi:10.1002/anie.202213422

Grignard, B., Mampuys, P., Escudero, J., Masullo, D., Lemière, F., Maes, B. U. W., & Detrembleur, C. (08 November 2022). Functional regioregular (poly)urethanes from soft nucleophiles and cyclic iminocarbonates. Polymer Chemistry, 13 (48), 6599 - 6605. doi:10.1039/d2py01077a

Penoy, N., Delma, K. L., Tonakpon, H. A., Grignard, B., Evrard, B., & Piel, G. (October 2022). An innovative one step green supercritical CO2 process for the production of liposomes co-encapsulating both a hydrophobic and a hydrophilic compound for pulmonary administration. International Journal of Pharmaceutics, 627, 122212. doi:10.1016/j.ijpharm.2022.122212

Raj, A., Panchireddy, S., Grignard, B., Detrembleur, C., & Gohy, J.-F. (20 September 2022). Bio-Based Solid Electrolytes Bearing Cyclic Carbonates for Solid-State Lithium Metal Batteries. ChemSusChem, 15 (18), 202200913. doi:10.1002/cssc.202200913

Siragusa, F., Habets, T., Méreau, R., Evano, G., Grignard, B., & Detrembleur, C. (23 June 2022). Catalyst-Free Approach for the Degradation of Bio- and CO<sub>2</sub>-Sourced Polycarbonates: A Step toward a Circular Plastic Economy. ACS Sustainable Chemistry and Engineering, 10 (27), 8863-8875. doi:10.1021/acssuschemeng.2c01891

Habets, T., Siragusa, F., Müller, A. J., Grossman, Q., Ruffoni, D., Grignard, B., & Detrembleur, C. (07 June 2022). Facile construction of functional poly(monothiocarbonate) copolymers under mild operating conditions. Polymer Chemistry, 13 (21), 3076-3090. doi:10.1039/d2py00307d

Siragusa, F., Demarteau, J., Habets, T., Olazabal, I., Robeyns, K., Evano, G., Mereau, R., Tassaing, T., Grignard, B., Sardon, H., & Detrembleur, C. (01 June 2022). Unifying Step-Growth Polymerization and On-Demand Cascade Ring-Closure Depolymerization via Polymer Skeletal Editing. Macromolecules, 55 (11), 4637-4646. doi:10.1021/acs.macromol.2c00696

Ngassam Tounzoua, C., Grignard, B., & Detrembleur, C. (23 May 2022). Exovinylene Cyclic Carbonates: Multifaceted CO2‐Based Building Blocks for Modern Chemistry and Polymer Science. Angewandte Chemie International Edition, 61 (22), 202116066. doi:10.1002/anie.202116066

Li, X., Villar-Yanez, A., Ngassam Tounzoua, C., Benet-Buchholz, J., Grignard, B., Bo, C., Detrembleur, C., & Kleij, A. W. (15 February 2022). Cascade transformation of carbon dioxide and alkyne-1,n-diols into densely substituted cyclic carbonates. ACS Catalysis, 12 (5), 2854-2860. doi:10.1021/acscatal.1c05773

Monie, F.* , Grignard, B.* , & Detrembleur, C.*. (15 February 2022). Divergent aminolysis approach for constructing recyclable self-blown nonisocyanate polyurethane foams. ACS Macro Letters, 11 (2), 236-242. doi:10.1021/acsmacrolett.1c00793
* These authors have contributed equally to this work.

Brege, A., Grignard, B., Méreau, R., Detrembleur, C., Jérôme, C., & Tassaing, T. (20 January 2022). En route to CO2-based (a)cyclic carbonates and polycarbonates from alcohols substrates by direct and indirect approaches. Catalysts, 12 (2), 124. doi:10.3390/catal12020124

Gomez-Lopez, A., Ayensa, N., Grignard, B., Irusta, L., Iñigo, C., Müller, A. J., Detrembleur, C., & Sardon, H. (10 January 2022). Enhanced and reusable poly(hydroxy urethane)-based low temperature hot-melt adhesives. ACS Applied Polymer Materials, 2 (3), 194.207. doi:10.1021/acspolymersau.1c00053

Delma, K. L., Penoy, N., Grignard, B., Semdé, R., Evrard, B., & Piel, G. (January 2022). Effects of supercritical carbon dioxide under conditions potentially conducive to sterilization on physicochemical characteristics of a liposome formulation containing apigenin. Journal of Supercritical Fluids, 179, 105418. doi:10.1016/j.supflu.2021.105418

Gomez-Lopez, A., Grignard, B., Calvo, I., Detrembleur, C., & Sardon, H. (2022). Accelerating the Curing of Hybrid Poly(Hydroxy Urethane)-Epoxy Adhesives by the Thiol-Epoxy Chemistry. ACS Applied Polymer Materials, 4 (12), 8786-8794. doi:10.1021/acsapm.2c01195

Gomez-Lopez, A., Panchireddy, S., Grignard, B., Calvo, I., Jérôme, C., Detrembleur, C., & Sardon, H. (26 July 2021). Poly(hydroxyurethane) adhesives and coatings: state-of-the-art and future directions. ACS Sustainable Chemistry and Engineering, 9 (28), 9541-9562. doi:10.1021/acssuschemeng.1c02558

Monie, F., Vidil, T., Grignard, B., Cramail, H., & Detrembleur, C. (July 2021). Self-foaming polymers: opportunities for the next generation of personal protective equipment. Materials Science and Engineering: R: Reports, 145, 100628. doi:10.1016/j.mser.2021.100628

Scholten, P. B. V., Cartigny, G., Grignard, B., Debuigne, A., Cramail, H., Meier, M. A. R., & Detrembleur, C. (16 March 2021). Functional polyethylenes by organometallic-mediated radical polymerization of biobased carbonates. ACS Macro Letters, 10 (3), 313-320. doi:10.1021/acsmacrolett.1c00037

Bourguignon, M., Thomassin, J.-M., Grignard, B., Vertruyen, B., & Detrembleur, C. (February 2021). Water-borne isocyanate-free polyurethane hydrogels with adaptable functionality and behavior. Macromolecular Rapid Communications, 42 (3), 2000482. doi:10.1002/marc.202000482

Siragusa, F., Van Den Broeck, E., Ocando, C., Müller, A. J., De Smet, G., Maes, B. U. W., De Winter, J., Van Speybroeck, V., Grignard, B., & Detrembleur, C. (01 February 2021). Access to biorenewable and CO2‑based polycarbonates from exovinylene cyclic carbonates. ACS Sustainable Chemistry and Engineering, 9 (4), 1714-1728. doi:10.1021/acssuschemeng.0c07683

Bourguignon, M., Grignard, B., & Detrembleur, C. (2021). Introducing polyhydroxyurethane hydrogels and coatings for formaldehyde capture. ACS Applied Materials and Interfaces, 13 (45), 54396-54408. doi:10.1021/acsami.1c16917

Gomez-Lopez, A., Grignard, B., Calvo, I., Detrembleur, C., & Sardon, H. (2021). Synergetic effect of dopamine and alkoxysilanes in sustainable non-isocyanate polyurethane adhesives. Macromolecular Rapid Communications, 42, 2000538. doi:10.1002/marc.202000538

Penoy, N., Grignard, B., Evrard, B., & Piel, G. (2021). A supercritical fluid technology for liposome production and comparison with the film hydration method. International Journal of Pharmaceutics, 592, 120093. doi:10.1016/j.ijpharm.2020.120093

Monie, F., Grignard, B., Thomassin, J.-M., Méreau, R., Tassaing, T., Jérôme, C., & Detrembleur, C. (21 September 2020). Chemo- and regio-selective additions of nucleophiles to cyclic carbonates for the preparation of self-blowing non-isocyanate polyurethane foams. Angewandte Chemie International Edition, 59 (39), 17033-17041. doi:10.1002/anie.202006267

Habets, T., Siragusa, F., Grignard, B., & Detrembleur, C. (11 August 2020). Advancing the synthesis of isocyanate-free poly(oxazolidones)s: scope and limitations. Macromolecules, 53 (15), 6393-6408. doi:10.1021/acs.macromol.0c01231

Ngassam Tounzoua, C., Grignard, B., Brege, A., Jérôme, C., Tassaing, T., Méreau, R., & Detrembleur, C. (06 July 2020). A catalytic domino approach towards oxo-alkyl carbonates and polycarbonates from CO2, propargylic alcohols and (mono- and di-) alcohols. ACS Sustainable Chemistry and Engineering, 8 (26), 9698-9710. doi:10.1021/acssuschemeng.0c01787

Koch, N., Jennotte, O., Grignard, B., Lechanteur, A., & Evrard, B. (01 July 2020). Impregnation of mesoporous silica with poor aqueous soluble molecule using pressurized carbon dioxide: is the solubility in the supercritical and subcritical phase a critical parameter? European Journal of Pharmaceutical Sciences, 150, 105332. doi:10.1016/j.ejps.2020.105332

Gomez-Lopez, A., Grignard, B., Calvo, I., Detrembleur, C., & Sardon, H. (08 May 2020). Monocomponent non-isocyanate polyurethane adhesives based on a sol-gel process. ACS Applied Polymer Materials, 2 (5), 1839-1847. doi:10.1021/acsapm.0c00062

Brege, A., Méreau, R., McGehee, K., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (May 2020). The coupling of CO2 with diols promoted by organic dual systems: Towards products divergence via benchmarking of the performance metrics. Journal of CO2 Utilization, 38, 88-98. doi:10.1016/j.jcou.2020.01.003

Ouhib, F., Meabe, L., Mahmoud, A., Grignard, B., Thomassin, J.-M., Boschini, F., Zhu, H., Forsyth, M., Mecerreyes, D., & Detrembleur, C. (14 February 2020). Influence of the cyclic vs. linear carbonate segments in the properties and performance of CO2-sourced polymer electrolytes for lithium batteries. ACS Applied Polymer Materials, 2 (2), 922-931. doi:10.1021/acsapm.9b01130

Léonard, G. L.-M., Pirard, S., Belet, A., Grignard, B., Detrembleur, C., Jérôme, C., & Heinrichs, B. (01 September 2019). Optimizing support properties of heterogeneous catalysts for the coupling of carbon dioxide with epoxides. Chemical Engineering Journal, 371, 719-729. doi:10.1016/j.cej.2019.04.055

Grignard, B., Gennen, S., Jérôme, C., Kleij, A. W., & Detrembleur, C. (21 August 2019). Advances in the use of CO2 as a renewable feedstock for the synthesis of polymers. Chemical Society Reviews, 48 (16), 4466-4514. doi:10.1039/c9cs00047j

Ouhib, F., Grignard, B., Van den Broeck, E., Luxen, A., Robeyns, K., Van Speybroeck, V., Jérôme, C., & Detrembleur, C. (19 August 2019). A switchable domino process for the construction of novel CO2- sourced sulfur-containing building blocks and polymers. Angewandte Chemie International Edition, 58 (34), 11768-11773. doi:10.1002/anie.201905969

Léonard, G. L.-M., Belet, A., Grignard, B., Calberg, C., Gilbert, B., Jérôme, C., & Heinrichs, B. (15 August 2019). Heterogenization of a cyclocarbonation catalyst: optimization and kinetic study. Catalysis Today, 334, 140-155. doi:10.1016/j.cattod.2018.11.060

Bourguignon, M., Thomassin, J.-M., Grignard, B., Jérôme, C., & Detrembleur, C. (15 July 2019). Fast and facile one-pot one-step preparation of non-isocyanate polyurethane hydrogels in water at room temperature. ACS Sustainable Chemistry and Engineering, 7 (14), 12601-12610. doi:10.1021/acssuschemeng.9b02624

Ouhib, F., Meabe, L., Mahmoud, A., Eshraghi, N., Grignard, B., Thomassin, J.-M., Aqil, A., Boschini, F., Jérôme, C., Mecerreyes, D., & Detrembleur, C. (28 April 2019). CO2-sourced polycarbonates as solid electrolytes for room temperature operation lithium battery. Journal of Materials Chemistry A, 7 (16), 9844-9853. doi:10.1039/C9TA01564G

Gennen, S., Grignard, B., Jérôme, C., & Detrembleur, C. (22 January 2019). CO2-sourced non-isocyanate poly(urethane)s with pH-sensitive imine linkages. Advanced Synthesis and Catalysis, 361 (2), 355-365. doi:10.1002/adsc.201801230

Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (05 November 2018). Catechol containing polyhydroxyurethanes as high-performance coatings and adhesives. ACS Sustainable Chemistry and Engineering, 6 (11), 14936-14944. doi:10.1021/acssuschemeng.8b03429

Grignard, B., Ngassam Tounzoua, C., Gennen, S., Gilbert, B., Méreau, R., Jérôme, C., Tassaing, T., & Detrembleur, C. (21 June 2018). Boosting the catalytic performance of organic salts for the fast and selective synthesis of α-alkylidene cyclic carbonates from CO2 and propargylic alcohols. ChemCatChem, 10 (12), 2584-2592. doi:10.1002/cctc.201800063

Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (08 May 2018). Merging CO2‑based building blocks with cobalt-mediated radical polymerization for the synthesis of functional poly(vinyl alcohol)s. Macromolecules, 51 (9), 3379-3393. doi:10.1021/acs.macromol.8b00492

Méreau, R., Grignard, B., Boyaval, A., Detrembleur, C., Jérôme, C., & Tassaing, T. (07 March 2018). Tetrabutyl ammonium salts: cheap catalysts for the facile and selective synthesis of a-alkylidene cyclic carbonates from CO2 and alkynol. ChemCatChem, 10 (5), 956-960. doi:10.1002/cctc.201701567

Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (2018). Bio-based poly(hydroxyurethane) glues for metal substrates. Polymer Chemistry, 9, 2650-2659. doi:10.1039/c8py00281a

Panchireddy, S., Thomassin, J.-M., Grignard, B., Damblon, C., Tatton, A., Jérôme, C., & Detrembleur, C. (14 October 2017). Reinforced poly(hydroxyurethane) thermosets as high performance adhesives for aluminum substrates. Polymer Chemistry, 8 (38), 5897-5909. doi:10.1039/C7PY01209H

Grignard, B., De Winter, J., Gerbaux, P., Gilbert, B., Jérôme, C., & Detrembleur, C. (October 2017). Merging supercritical carbon dioxide and organocatalysis for the precision and green synthesis of poly(lactide)-based (co)polymers. European Polymer Journal, 95, 635-649. doi:10.1016/j.eurpolymj.2017.03.061

Zaky, M., Boyaval, A., Grignard, B., Méreau, R., Detrembleur, C., Jérôme, C., & Tassaing, T. (October 2017). On the phase behaviour of oxetane-CO2 and propargylic alcohols-CO2 binary mixtures by in situ infrared micro-spectrometry. Journal of Supercritical Fluids, 128, 308-313. doi:10.1016/j.supflu.2017.03.009

Gennen, S., Grignard, B., Tassaing, T., Jérôme, C., & Detrembleur, C. (21 August 2017). CO2-sourced α-alkylidene cyclic carbonates: a Step forward in the quest for functional regioregular poly(urethane)s and poly(carbonate)s. Angewandte Chemie International Edition, 56 (35), 10394–10398. doi:10.1002/anie.201704467

Parilti, R., Alaimo, D., Grignard, B., Boury, F., Howdle, S. M., & Jérôme, C. (07 August 2017). Mild synthesis of poly(HEMA)-networks as well-defined nanoparticles in supercritical carbon dioxide. Journal of Materials Chemistry B, 5 (29), 5806-5815. doi:10.1039/c7tb00740j

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (31 March 2017). DFT investigation of the reaction mechanism for the guanidine catalyzed ring-opening of cyclic carbonates by aromatic and alkyl-amines. RSC Advances, 7 (31), 18993-19001. doi:10.1039/c7ra00220c

Alves, M., Grignard, B., Boyaval, A., Méreau, R., De Winter, J., Gerbaux, P., Detrembleur, C., Tassaing, T., & Jérôme, C. (22 March 2017). Organocatalytic coupling of CO2 with oxetane. ChemSusChem, 10 (6), 1128-1138. doi:10.1002/cssc.201601185

Boyaval, A., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (22 March 2017). Organocatalytic coupling of CO2 with a propargylic alcohol: a comprehensive study of the reaction mechanism combining in- situ ATR-IR spectroscopy and DFT calculations. ChemSusChem, 10 (6), 1241-1248. doi:10.1002/cssc.201601524

Alaimo, D., Grignard, B., Kuppan, C., Adriaensen, Y., Genet, M. J., Dupont-Gillain, C., Gohy, J.-F., Fustin, C.-A., Detrembleur, C., & Jérôme, C. (21 January 2017). Photocleavable stabilizer for the preparation of PHEMA nanogels by dispersion polymerization in supercritical carbon dioxide. Polymer Chemistry, 8 (3), 581-591. doi:10.1039/C6PY01633B

Alves, M., Grignard, B., Méreau, R., Jérôme, C., Tassaing, T., & Detrembleur, C. (2017). Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies. Catalysis Science and Technology, 7, 2651-2684. doi:10.1039/C7CY00438A

Gennen, S., Grignard, B., Thomassin, J.-M., Gilbert, B., Vertruyen, B., Jérôme, C., & Detrembleur, C. (November 2016). Polyhydroxyurethane hydrogels: synthesis and characterizations. European Polymer Journal, 84, 849-862. doi:10.1016/j.eurpolymj.2016.07.013

Grignard, B., Thomassin, J.-M., Gennen, S., Poussard, L., Bonnaud, L., Raquez, J.-M., Dubois, P., Tran, M.-P., Park, C. B., Jérôme, C., & Detrembleur, C. (07 April 2016). CO2-blown microcellular non-isocyanate polyurethane (NIPU) foams: from bio- and CO2-sourced monomers to potentially thermal insulating materials. Green Chemistry, 18 (7), 2206-2215. doi:10.1039/C5GC02723C

Poussard, L., Mariage, J., Grignard, B., Detrembleur, C., Jérôme, C., Calberg, C., Heinrichs, B., De Winter, J., Gerbaux, P., Raquez, J.-M., Bonnaud, L., & Dubois, P. (22 March 2016). Non-isocyanate polyurethanes from carbonated soybean oil Using monomeric or oligomeric diamines To achieve thermosets or thermoplastics. Macromolecules, 49 (6), 2162-2171. doi:10.1021/acs.macromol.5b02467

Kermagoret, Chau, N. D. Q., Grignard, B., Cordella, D., Debuigne, A., Jérôme, C., & Detrembleur, C. (March 2016). Cobalt-mediated radical polymerization of vinyl acetate and acrylonitrile in supercritical carbon dioxide. Macromolecular Rapid Communications, 39 (6), 539-544. doi:10.1002/marc.201500629

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (2016). A comprehensive density functional theory study of the key role of fluorination and dual hydrogen bonding in the activation of the epoxide/CO2 coupling by fluorinated alcohols. RSC Advances, 6 (43), 36327-36335. doi:10.1039/C6RA03427F

Galia, A., Scialdone, O., Spanò, T., Valenti, M. G., Grignard, B., Lecomte, P., Monflier, E., Tilloy, S., & Rousseau, C. (2016). Ring opening polymerization of ε-caprolactone in the presence of wet β-cyclodextrin: effect of the operative pressure and of water molecules in the β-cyclodextrin cavity. RSC Advances, 6, 90290-90299. doi:10.1039/C6RA20211J

Alves, M., Grignard, B., Gennen, S., Méreau, R., Detrembleur, C., Jérôme, C., & Tassaing, T. (01 September 2015). Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors. Catalysis Science and Technology, 5 (9), 4636-4643. doi:10.1039/C5CY00891C

Gennen, S., Alves, M., Méreau, R., Tassaing, T., Gilbert, B., Detrembleur, C., Jérôme, C., & Grignard, B. (08 June 2015). Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides. ChemSusChem, 8 (11), 1845-1849. doi:10.1002/cssc.201500103

Alaimo, D., Hermida Merino, D., Grignard, B., Bras, W., Jérôme, C., Debuigne, A., & Gommes, C. (2015). Small Angle X-ray Scattering Insights into the Architecture-Dependent Emulsifying Properties of Amphiphilic Copolymers in Supercritical Carbon Dioxide. Journal of Physical Chemistry B, 119, 1706-1716. doi:10.1021/jp5086558

Alves, M., Grignard, B., Gennen, S., Detrembleur, C., Jérôme, C., & Tassaing, T. (2015). Organocatalytic synthesis of bio-based cyclic carbonates from CO2 and vegetable oils. RSC Advances, 5, 53629-53636. doi:10.1039/C5RA10190E

Alaimo, D., Beigbeder, A., Dubois, P., Broze, G., Jérôme, C., & Grignard, B. (21 September 2014). Block, random and palm-tree amphiphilic fluorinated copolymers: controlled synthesis, surface activity and use as dispersion polymerization stabilizers. Polymer Chemistry, 5 (18), 5273-5282. doi:10.1039/C4PY00366G

Liu, J., Detrembleur, C., Grignard, B., De Pauw-Gillet, M.-C., Mornet, S., Treguer-Delapierre, M., Petit, Y., Jérôme, C., & Duguet, E. (January 2014). Gold nanorods with phase-changing polymer corona for remotely near-infrared-triggered drug release. Chemistry: An Asian Journal, 9 (1), 275-288. doi:10.1002/asia.201301010

Boyère, C., Léonard, A., Grignard, B., Favrelle, A., Pirard, J.-P., Paquot, M., Jérôme, C., & Debuigne, A. (28 August 2012). Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide. Chemical Communications, 48 (67), 8356-8358. doi:10.1039/c2cc33978a

Grignard, B., Gilbert, B., Malherbe, C., Jérôme, C., & Detrembleur, C. (06 August 2012). Online monitoring of heterogeneous polymerizations in supercritical carbon dioxide by Raman spectroscopy. Chemphyschem: A European Journal of Chemical Physics and Physical Chemistry, 13 (11), 2666-2670. doi:10.1002/cphc.201200373

Clement, B., Grignard, B., Koole, L., Jérôme, C., & Lecomte, P. (12 June 2012). Metal-free strategies for the synthesis of functional and well-defined polyphosphoesters. Macromolecules, 45 (11), 4476-4486. doi:10.1021/ma3004339

Grignard, B., Vaillant, A., de Coninck, J., Piens, M., Jonas, A. M., Detrembleur, C., & Jérôme, C. (04 January 2011). Electrospinning of a functional perfluorinated block copolymer as a powerful route for imparting superhydrophobicity and corrosion resistance to aluminum substrates. Langmuir, 27 (1), 335-342. doi:10.1021/la102808w

Awada, H., Grignard, B., Jérôme, C., Vaillant, A., De Coninck, J., Nysten, B., & Jonas, A. M. (07 December 2010). Correlation between superhydrophobicity and the power spectral density of randomly rough surfaces. Langmuir, 26 (23), 17798-17803. doi:10.1021/la104282q

Grignard, B., Calberg, C., Jérôme, C., & Detrembleur, C. (June 2010). “One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres. Journal of Supercritical Fluids, 53 (1-3), 151-155. doi:10.1016/j.supflu.2009.12.014

Grignard, B., Phan, T., Bertin, D., Gigmes, D., Jérôme, C., & Detrembleur, C. (June 2010). Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers. Polymer Chemistry, 1 (6), 837-840. doi:10.1039/c0py00066c

Desbief, S., Grignard, B., Detrembleur, C., Rioboo, R., Vaillant, A., Seveno, D., Voué, M., De Coninck, J., Jonas, A. M., Jérôme, C., Damman, P., & Lazzaroni, R. (02 February 2010). Superhydrophobic aluminum surfaces by deposition of micelles of fluorinated block copolymers. Langmuir, 26 (3), 2057-2067. doi:10.1021/la902565y

Grignard, B., Schmeits, S., Riva, R., Detrembleur, C., Lecomte, P., & Jérôme, C. (November 2009). First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters. Green Chemistry, 11, 1525-1529. doi:10.1039/b822924d

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., Wang, W., Howdle, S. M., & Detrembleur, C. (25 November 2008). Dispersion Atom Transfer Radical Polymerization of vinyl monomers in supercritical carbon dioxide. Macromolecules, 41 (22), 8575-8563. doi:10.1021/ma801474s

Grignard, B., Stassin, F., Calberg, C., Jérôme, R., & Jérôme, C. (10 November 2008). Synthesis of biodegradable poly-epsilon-caprolactone microspheres by dispersion ring-opening polymerization in supercritical carbon dioxide. Biomacromolecules, 9 (11), 3141-3149. doi:10.1021/bm800730m

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (March 2008). Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide. European Polymer Journal, 44 (3), 861-871. doi:10.1016/j.eurpolymj.2007.11.020

Grignard, B., Calberg, C., Jérôme, C., Wang, W., Howdle, S., & Detrembleur, C. (2008). Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues. Chemical Communications, (44), 5803-5805. doi:10.1039/b812297k

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., Wang, W., Howdle, S. M., & Detrembleur, C. (2008). Copper bromide complexed by fluorinated macroligands: towards microspheres by ATRP of vinyl monomers in scCO2. Chemical Communications, (3), 314-316. doi:10.1039/b716208a

Ocando, C., Serrano, E., Tercjak, A., Pena, C., Kortaberria, G., Calberg, C., Grignard, B., Jérôme, R., Carrasco, P. M., Mecerreyes, D., & Mondragon, I. (29 May 2007). Structure and properties of a semifluorinated diblock copolymer modified epoxy blend. Macromolecules, 40 (11), 4068-4074. doi:10.1021/ma070585i

Grignard, B., Jérôme, C., Calberg, C., Detrembleur, C., & Jérôme, R. (15 April 2007). Controlled synthesis of carboxylic acid end-capped poly(heptadecafluorodecyl acrylate) and copolymers with 2-hydroxyethyl acrylate. Journal of Polymer Science. Part A, Polymer Chemistry, 45 (8), 1499-1506. doi:10.1002/pola.21920

Etienne, S., Becker, C., Ruch, D., Grignard, B., Cartigny, G., Detrembleur, C., Calberg, C., & Jérôme, R. (January 2007). Effects of incorporation of modified silica nanoparticles on the mechanical and thermal properties of PMMA. Journal of Thermal Analysis and Calorimetry, 87 (1), 101-104. doi:10.1007/s10973-006-7827-4

Patents

Detrembleur, C., Grignard, B., & Bourguignon, M. (15 June 2023). Self-blowing isocyanate-free polyurethane foams.

Detrembleur, C., Thomassin, J.-M., Grignard, B., Monie, F., & Jérôme, C. (14 January 2021). Self-blowing isocyanate free polyurethane foams.

Scientific conferences in universities or research centers

Léonard, G., Toye, D., & Grignard, B. (January 2016). Reactors for CO2 utilization [Paper presentation]. Visit to the University of Edinburgh.

Scientific congresses and symposiums

Oral communications or posters

Habets, T., Grignard, B., & Detrembleur, C. (26 January 2024). Dynamic N,S-acetal chemistry: toward recyclable CO2-based thermosets [Paper presentation]. EDT-CHIM 2024.

Habets, T., Detrembleur, C., & Grignard, B. (17 January 2024). CO2 as a building block toward sustainable and circular plastics [Paper presentation]. FRITCO2T DAY.

Koch, N., Jennotte, O., Lechanteur, A., Grignard, B., & Evrard, B. (17 January 2024). Improvement of aqueous solubility of active pharmaceutical ingredients by using mesoporous silica impregnation under pressurized carbon dioxide [Paper presentation]. 1st FRITCO2T Day.

Penoy, N., Delma, K. L., Grignard, B., Evrard, B., & Piel, G. (23 May 2023). The use of supercritical CO2 to develop liposomes encapsulating active pharmaceutical ingredients for pulmonary administration [Poster presentation]. 19th European Meeting on Supercritical Fluids, Budapest, Hungary.

Habets, T., Grignard, B., & Detrembleur, C. (22 May 2023). Poly(oxazolidone)s as the Next Generation of Non-isocyanate Polyurethanes: A Novel Approach toward Recyclable Advanced Materials [Paper presentation]. BPG 2023, Houffalize, Belgium.

Penoy, N., Delma, K. L., EGREK, S., Grignard, B., Sacheli, R., Sacre, P.-Y., Hayette, M.-P., Evrard, B., & Piel, G. (27 April 2023). Supercritical CO2 to produce and sterilize liposomes: How to find supercritical parameters with the QbD strategy [Paper presentation]. BSPS - 20th Forum of Pharmaceutical Sciences, Blankerberge, Belgium.

Habets, T., Grignard, B., & Detrembleur, C. (13 April 2023). Poly(oxazolidone)s as the Next Generation of Non-Isocyanate Polyurethanes — A Facile Access to Recyclable Advanced Materials [Paper presentation]. 2023 MRS Spring Meeting, San Francisco, United States.

Habets, T., Siragusa, F., Müller, A., Grignard, B., & Detrembleur, C. (14 November 2022). Poly(oxazolidone)s hybrid polymers as the next generation of non-isocyanate polyurethanes [Poster presentation]. BPG 2022, Blankenberge, Belgium.

Habets, T., Siragusa, F., Grignard, B., Detrembleur, C., & Müller Alejandro. (08 May 2022). Poly(oxazolidone)s as the next generation of non-isocyanate polyurethanes [Poster presentation]. GEP-SLAP 2022, San Sebastián, Spain.

Delma, K. L., Delma, K. L., Penoy, N., Grignard, B., Semdé, R., Evrard, B., & Piel, G. (29 March 2022). Effects of supercritical carbon dioxide under conditions potentially conducive to sterilization on chemical stability of phospholipids and physicochemical characteristics of a liposome formulation [Poster presentation]. 13th World Meeting on Pharmaceutics, Biopharmaceutics and Pharmaceutical Technology, Rotterdam, Netherlands.

Delma, K. L., Delma, K. L., Penoy, N., Grignard, B., Semdé, R., Evrard, B., & Piel, G. (02 February 2022). Applicability of supercritical carbon dioxide sterilization to liposomes: effects of potential conditions on phospholipids and liposomes stability [Paper presentation]. CIRM day 2022, Liège, Belgium.

Detrembleur, C., Siragusa, F., Habets, T., Monie, F., Bourguignon, M., Jérôme, C., & Grignard, B. (19 April 2021). Carbon Dioxide for Producing Non-Isocyanate Polyurethane Foams, Adhesives, Hydrogels and—Much More! [Paper presentation]. Materials Research Society (MRS) Spring Virtual Meeting - Progress in Green Chemistry Approaches for Sustainable Polymer Materials I, Virtual Meeting, United States.

Penoy, N., Grignard, B., Evrard, B., & Piel, G. (06 April 2021). Double Encapsulation in liposomes for pulmonary administration produced by an innovative supercritical process [Paper presentation]. Controlled Release Society BeNeLux&France Early Career Scientists Meeting (online).

Penoy, N., Grignard, B., Evrard, B., & Piel, G. (04 March 2021). A supercritical PGSS method to encapsulate budesonide in liposome: comparison with the classical tFH method [Paper presentation]. CRS Local Chapters Meeting Germany and BeNeLux & France (online).

Penoy, N., Koch, N., Grignard, B., Evrard, B., & Piel, G. (March 2021). The quality by design strategy to prepare different liposomes formulations by a new supercritical fluid method [Poster presentation]. APGI Meeting on Pharmaceutics, Biopharmaceutics and Pharmaceutical Technology.

Ngassam Tounzoua, C., Grignard, B., Jérôme, C., Tassaing, T., & Detrembleur, C. (24 September 2019). Dual activation catalysts for the selective conversion of CO2 into alkylidene cyclic carbonates and oxoalkyl carbonates [Paper presentation]. European Chemical Society (EuCHeMS) conference on Green and Sustainable Chemistry, Tarragona, Spain.

Brege, A., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (23 September 2019). CO2-based monomers: a detailed investigation of the carbonation reaction over diols for the synthesis of (a)cyclic carbonates promoted by organic dual systems [Poster presentation]. European Chemical Society (EuCHeMS) conference on Green and Sustainable Chemistry, Tarragona, Spain.

Grignard, B., Gennen, S., Ngassam Tounzoua, C., Ouhib, F., Jérôme, C., & Detrembleur, C. (26 June 2019). Upgrading CO₂ into novel families of regioregular and functional polymers [Paper presentation]. International Conference on Carbon Dioxide Utilization (ICCDU), Aachen, Germany.

Brege, A., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (25 June 2019). International Conference on Carbon Dioxide Utilization (ICCDU) [Paper presentation]. International Conference on Carbon Dioxide Utilization (ICCDU), Aachen, Germany.

Ngassam Tounzoua, C., Grignard, B., Jérôme, C., Tassaing, T., & Detrembleur, C. (June 2019). Cooperative catalysts for the selective synthesis of alkylidene cyclic carbonates from CO2 and propargylic alcohols [Poster presentation]. International Conference on Carbon Dioxide Utilization (ICCDU), Aachen, Germany.

Bourguignon, M., Thomassin, J.-M., Grignard, B., Jérôme, C., & Detrembleur, C. (28 May 2019). Synthesis of waterborne non-isocyanate polyhydroxyurethane hydrogel [Paper presentation]. Belgian Polymer Group (BPG) Annual Meeting, Houffalize, Belgium.

Brege, A., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (27 May 2019). Mechanistic and kinetic insight into the carbonatation reaction of diols to afford (a)cyclic carbonates: toward CO2-based monomers [Poster presentation]. Belgian Polymer Group (BPG) Annual Meeting, Houffallize, Belgium.

Toullec, C., Boury, F., Grignard, B., Buchtová, N., Le Bideau, J., Terrisse, H., & Jérôme, C. (27 May 2019). Synthesis of new PLGA based grafted polymers for formation of bioactive nanoparticles [Poster presentation]. Belgian Polymer Group (BPG) Annual Meeting, Houffallize, Belgium.

Bourguignon, M., Thomassin, J.-M., Grignard, B., Jérôme, C., & Detrembleur, C. (23 May 2019). Poly(hydroxyurethane) hydrogels preparation in water at room temperature [Poster presentation]. European Polymer Federation (EPF) Summer School: Dynamic and Reversible Polymer Networks, Bertinoro, Italy.

Léonard, G., Belet, A., Grignard, B. (Other coll.), Calberg, C. (Other coll.), Gilbert, B. (Other coll.), & Heinrichs, B. (Other coll.). (09 July 2018). HETEROGENIZATION OF A CYCLOCARBONATION CATALYST [Poster presentation]. 12th International Symposium on the "Scientific Bases for the Preparation of Heterogeneous Catalysts", Louvain-La-Neuve, Belgium.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (20 June 2018). Sustainable poly(hydroxyurethane)s thermoset adhesives for affixing metals [Poster presentation]. Green Chemistry and Technology, Dublin, Ireland.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (18 June 2018). Sustainable poly(hydroxyurethane)s thermoset adhesives for affixing metals [Paper presentation]. Green Chemistry and Technology, Dublin, Ireland.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (29 May 2018). From CO2 to high performance adhesives for affixing metal substrates [Paper presentation]. Belgian Polymer Group (BPG) Annual Meeting, Blankenberge, Belgium.

Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (29 May 2018). Controlled radical (co)polymerisation of vinylic monomers originating from renewable resources [Poster presentation]. Bordeaux Polymer Conference, Borddeaux, France.

Scholten, P., Demarteau, J., Gennen, S., De Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (29 May 2018). Controlled radical (co)polymerisation of allylic- and vinylic monomers originating from renewable resources [Paper presentation]. Bordeaux Polymer Conference, Bordeaux, France.

Scholten, P., Demarteau, J., Gennen, S., de Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (22 March 2018). Controlled radical (co)polymerisation of allylic and vinylic monomers originating from renewable resources [Paper presentation]. The International Doctoral School in Functional Materials (EJD-FunMat) Training School, Luxembourg, Luxembourg.

Scholten, P., Demarteau, J., Gennen, S., de Winter, J., Grignard, B., Debuigne, A., Meier, M. A. R., & Detrembleur, C. (21 March 2018). Investigation of the copolymerisation behaviour of bio-sourced vinylic and allylic cyclic carbonates [Poster presentation]. The International Doctoral School in Functional Materials (EJD-FunMat) Training School, Luxembourg, Luxembourg.

Gennen, S., Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (09 June 2017). Bio- and CO2-sourced polyhydroxyurethanes for hydrogels coatings, foams and high performance adhesives [Poster presentation]. CESAM Research Unit Day, Liège, Belgium.

Grignard, B., Detrembleur, C., & Jérôme, C. (09 June 2017). Carbon dioxide transformation and reuse: challenges & opportunities [Paper presentation]. CESAM Research Unit Day, Liège, Belgium.

Grignard, B., Poussard, L., Raquez, J.-M., Dubois, P., Jérôme, C., & Detrembleur, C. (22 May 2017). Merging CO2 transformation and utilization with renewable bio-resources: a step forward to a double vision of sustainable chemistry [Paper presentation]. Green chemistry and White biotechnology: Industry of the future, Mons, Belgium.

Gennen, S., Grignard, B., Alves, M., Thomassin, J.-M., Tassaing, T., Jérôme, C., & Detrembleur, C. (04 May 2017). How to exploit bio- and CO2-based isocyanates-free polyurethanes for environmental and biomedical applications? [Poster presentation]. Belgian Polymer Group (BPG) Annual Meeting, Houffalize, Belgium.

Ngassam Tounzoua, C. G., Gilbert, B., Detrembleur, C., Jérôme, C., Boyaval, A., Tassaing, T., & Grignard, B. (04 May 2017). Simple, cheap but highly efficient organo catalysts for the fixation of CO2 on propargylic alcohols [Poster presentation]. Belgian Polymer Group (BPG) Annual Meeting, Houffalize, Belgium.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (04 May 2017). Reinforced poly(hydroxyurethane) coatings and high performance adhesive [Poster presentation]. Belgian Polymer Group (BPG) Annuel Meeting, Houffalize, Belgium.

Detrembleur, C., Alves, M., Grignard, B., Gennen, S., Panchireddy, S., Méreau, R., Tassaing, T., & Jérôme, C. (21 March 2017). Oils and CO2, a promising combination for designing insulating foams and high performance coatings [Paper presentation]. Workshop on Fats and Oils as Renewable Feedstock for the Chemical Industry, Karlsruhe, Germany.

Scholten, P., Demarteau, J., Debuigne, A., Grignard, B., Meier, M. A. R., & Detrembleur, C. (March 2017). Investigation of the copolymerization behavior of a cyclic carbonate with vinyl acetate using CMRP [Poster presentation]. International Doctoral School EJD-Funmat, Aveiro, Portugal.

Gennen, S., Grignard, B., Thomassin, J.-M., Gilbert, B., Vertruyen, B., Jérôme, C., & Detrembleur, C. (13 October 2016). Synthesis and characterization of non-isocyanate polyurethane (NIPU) hydrogels [Poster presentation]. Journée de la Société Royale de Chimie (SRC), Liège, Belgium.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Alexis, R., Olivier, M., Poorteman, M., Detrembleur, C., & Jérôme, C. (13 October 2016). Novel promising way to synthesize non-isocyanate polyurethanes (NIPUs) for innovative coating applications against corrosion protection of metal surfaces [Poster presentation]. Journée de la Société Royale de Chimie (SRC), Liège, Belgium.

Detrembleur, C., Alves, M., Grignard, B., Gennen, S., Méreau, R., Tassaing, T., & Jérôme, C. (13 September 2016). Merging carbon dioxide utilization, bio-resources and CO2-based process for sustainable low carbon footprint polyurethanes [Paper presentation]. Organocatalysis and Sustainable Polymers European Joint Doctorate (SUSPOL EJD) Summer School, La Hulpe, Belgium.

Gennen, S., Grignard, B., Thomassin, J.-M., Gilbert, B., Vertruyen, B., & Jérôme, C. (12 September 2016). Synthesis and characterizations of non-isocyanate polyurethane (NIPU) hydrogels [Poster presentation]. PAI Annual Meeting, Liège, Belgium.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Renaud, A., Olivier, M., Poorteman, M., Detrembleur, C., & Jérôme, C. (12 September 2016). Environmentally friendly bio-based non-isocyanate (NIPU) coatings for corrosion protection of metal surfaces [Poster presentation]. PAI Annual Meeting, Liège, Belgium.

Gennen, S., Grignard, B., Thomassin, J.-M., Jérôme, C., Detrembleur, C., Tassaing, T., Alves, M., Panchireddy, S., Gilbert, B., & Vertruyen, B. (07 July 2016). Valorization of CO2 for the preparation of advanced materials [Paper presentation]. Chemistry Department Day, Liège, Belgium.

Alves, M., Grignard, B., Gennen, S., Méreau, R., Tassaing, T., Detrembleur, C., & Jérôme, C. (29 June 2016). Merging carbon dioxide utilisation, bioresources and CO2-based process for sustainable low carbon footprints polyurethanes [Poster presentation]. CO2 Utilisation as a Strong Catalyst for the European Industrial Renaissance (SCOT), Brussels, Belgium.

Gennen, S., Grignard, B., Thomassin, J.-M., Gilbert, B., Vertruyen, B., Jérôme, C., & Detrembleur, C. (29 June 2016). From CO2 to non-isocyanate polyurethane (NIPU) hydrogels with potential biomedical applications [Poster presentation]. CO2 Utilisation as a Strong Catalyst for the European Industrial Renaissance (SCOT), Brussels, Belgium.

Alves, M., Grignard, B., Boyaval, A., Gennen, S., Méreau, R., Tassaing, T., Detrembleur, C., De Winter, J., Gerbaux, P., & Jérôme, C. (24 May 2016). Catalytic transformation of CO2: from monomers to polymers [Paper presentation]. Belgian Polymer Group (BPG) Annual Meeting, Hasselt, Belgium.

Gennen, S., Grignard, B., Thomassin, J.-M., Gilbert, B., Vertruyen, B., Jérôme, C., & Detrembleur, C. (23 May 2016). Synthesis of CO2-sourced hydrogels by using the non-isocyanate polyurethane (NIPU) chemistry [Poster presentation]. Belgian Polymer Group (BPG) Annual Meeting, Hasselt, Belgium.

Panchireddy, S., Grignard, B., Thomassin, J.-M., Renaud, A., Olivier, M., Poorteman, M., Detrembleur, C., & Jérôme, C. (23 May 2016). Non-isocyanate polyurethanes (NIPUs) coating for corrosion protection of metal surfaces [Poster presentation]. Belgian Polymer Group (BPG) Annual Meeting, Hasselt, Belgium.

Alves, M., Grignard, B., Boyaval, A., Gennen, S., Méreau, R., Tassaing, T., Detrembleur, C., Dewinter, J., Gerbaux, P., & Jérôme, C. (20 April 2016). Cyclic and oligo-carbonates by organocatalytic coupling of CO2 with epoxides or oxetanes [Paper presentation]. Zing Conferences, Carbon Dioxide Catalysis, Albufeira, Portugal.

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (20 April 2016). On the key role of fluoration and dual hydrogen bonding in the activation of the epoxide/CO2 coupling by fluorinated alcohols : a DFT study [Poster presentation]. Zing Conferences, Carbon Dioxide Catalysis, Albufeira, Portugal.

Grignard, B., Gennen, S., Alves, M., Tassaing, T., Gilbert, B., Detrembleur, C., & Jérôme, C. (April 2016). CO2-based sustainable polymers: from CO2-sourced monomers to low CO2 emission foamed materials [Paper presentation]. Zing Conferences, Carbon Dioxide Catalysis, Albufeira, Portugal.

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (March 2016). Theoretical study of the organocatalyzed synthesis of NIPUs [Poster presentation]. International Doctoral School in Functional Materials (IDS-FunMat), Bordeaux, France.

Grignard, B., Gennen, S., Alves, M., Tassaing, T., Méreau, R., Gilbert, B., Jérôme, C., & Detrembleur, C. (19 December 2015). Organocatalytic coupling of carbon dioxide with epoxides: the unexpected booster effect of fluoroalcohols [Poster presentation]. Pacifichem, Honolulu, United States - Hawaii.

Panchireddy, S., Gennen, S., Alves, M., Tassaing, T., Grignard, B., Gilbert, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (11 September 2015). New efficient organocatalytic system for solvent-free chemical fixation of CO2 into epoxides [Poster presentation]. Annual PAI Meeting, Hasselt, Belgium.

Gennen, S., Grignard, B., Gilbert, B., Jérôme, C., & Detrembleur, C. (07 July 2015). CO2-sourced non-isocyanate polyurethanes: from the monomer synthesis to the elaboration of polymeric materials [Paper presentation]. International Conference on Carbon Dioxide Utilization (ICCDU), Singapore, Singapore.

Alves, M., Méreau, R., Grignard, B., Gennen, S., Detrembleur, C., Jérôme, C., & Tassaing, T. (06 July 2015). Efficient hydrogen-bond donor activators for the synthesis of bio-based cyclic carbonates from CO2 and vegetable oils: a combined in-situ FT-IR and DFT study [Paper presentation]. International Conference on Carbon Dioxide Utilization (ICCDU), Singapore, Singapore.

Panchireddy, S., Gennen, S., Alves, M., Tassaing, T., Grignard, B., Gilbert, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (02 July 2015). Fast synthesis of cyclic carbonates from epoxides and CO2 using an highly efficient organocatalytic system [Poster presentation]. Chemistry Department Day, Liège, Belgium.

Panchireddy, S., Gennen, S., Alves, M., Tassaing, T., Grignard, B., Gilbert, B., Thomassin, J.-M., Jérôme, C., & Detrembleur, C. (30 June 2015). Development of a highly efficient organocatalytic system for the synthesis of cyclic carbonates by coupling CO2 with epoxide [Poster presentation]. Researcher’s Day of the Materials Research Institute, Mons, Belgium.

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (18 May 2015). New efficient bicomponent organocatalysts for the chemical fixation of CO2 onto epoxides: a theoretical study [Poster presentation]. Belgian Polymer Group (BPG) Annuel Meeting, Houffalize, Belgium.

Gennen, S., Alves, M., Tassaing, T., Grignard, B., Gilbert, B., Detrembleur, C., & Jérôme, C. (18 May 2015). Non-isocyanate polyurethane: from the monomer synthesis to foamed materials [Poster presentation]. Belgian Polymer Group (BPG) Annuel Meeting, Houffalize, Belgium.

Parilti, R., Jérôme, C., Howdle, S. M., Detrembleur, C., Grignard, B., & Alaimo, D. (18 May 2015). Design of new multifunctional nanocarriers for protein delivery [Paper presentation]. Belgian Polymer Group (BPG) Annuel Meeting, Houffalize, Belgium.

Grignard, B., Alaimo, D., De Winter, J., Gerbaux, P., Detrembleur, C., & Jérôme, C. (07 May 2015). Sc-CO2-assisted melt polymerization: towards the synthesis of precision homo- and block copolymers by organocatalytic ring opening polymerization from lactides [Paper presentation]. International Symposium on Green Chemistry (ISGC), La Rochelle, France.

Gennen, S., Alves, M., Tassaing, T., Grignard, B., Gilbert, B., Detrembleur, C., & Jérôme, C. (03 May 2015). Carbon dioxide, a cheap bio-sourced building block for cyclic carbonates and non-isocyanate polyurethanes [Poster presentation]. International Symposium on Green Chemistry (ISGC), La Rochelle, France.

Alves, M., Gennen, S., Grignard, B., Detrembleur, C., Méreau, R., Jérôme, C., & Tassaing, T. (May 2015). New efficient organocatalyst for the synthesis of bio-based cyclic carbonates from CO2 and vegetable oil [Paper presentation]. International Symposium on Green Chemistry (ISGC), La Rochelle, France.

Parilti, R., Alaimo, D., Grignard, B., Detrembleur, C., Howdle, S. M., & Jérôme, C. (23 March 2015). Design of new multifunctional nanocarriers for protein delivery [Poster presentation]. Advanced Functional Polymer for Medicine (AFPM), Galway, Ireland.

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (18 March 2015). Carbon dioxide and vegetable ooil for the synthesis of bio-based polymer precursor [Paper presentation]. The International Doctoral School in Functional Materials (IDS FunMat) Training School, Vallendar, Germany.

Alves, M., Méreau, R., Grignard, B., Detrembleur, C., Jérôme, C., & Tassaing, T. (March 2015). Highly efficient hydrogen-bond donor activators for the metal free synthesis of bio-based cyclic carbonates under mild conditions [Poster presentation]. The International Doctoral School in Functional Materials (IDS FunMat) Training School, Vallendar, Germany.

Alves, M., Méreau, R., Grignard, B., Cramail, H., Jérôme, C., & Tassaing, T. (October 2014). On the use of carbon dioxide and vegetable oil for the synthesis of bio-based cyclic carbonates [Poster presentation]. Journées Francophones des Jeunes Physico-Chimistes (JFJPC), Dammarie-Les-Lys, France.

Alves, M., Tassaing, T., Méreau, R., Grignard, B., Cramail, H., & Jérôme, C. (27 August 2014). On the use of carbon dioxide and vegetable oil for the synthesis of bio-based cyclic carbonates [Paper presentation]. Conference on Engineering for Waste and Biomass Valorisation, Rio de Janeiro, Brazil.

Alves, M., Tassaing, T., Mereau, R., Grignard, B., Cramail, H., & Jérôme, C. (03 July 2014). On the use of carbon dioxide and vegetable oil for the synthesis of bio-based cyclic carbonates [Poster presentation]. Journée Scientifique de l'Insititut des Sciences des Matériaux de Bordeaux, Talence, France.

Parilti, R., Alaimo, D., Grignard, B., Howdle, S., Detrembleur, C., & Jérôme, C. (26 May 2014). Design of new multifunctional nanocarriers for proteins delivery [Poster presentation]. Advanced Functional Polymer for Medicine (AFPM), Lliège, Belgium.

Gennen, S., Grignard, B., Gilbert, B., Detrembleur, C., & Jérôme, C. (20 May 2014). Chemical fixation of CO2 with epoxides: towards the synthesis of cyclic carbonates, precursors of CO2-based polyurethanes [Poster presentation]. Belgian Polymer Group (BPG) Annuel Meeting, Ghent, Belgium.

Alves, M., Méreau, R., Grignard, B., Cramail, H., Jérôme, C., & Tassaaing, T. (March 2014). Organocatalyzed synthesis of cyclic carbonates from epoxidized vegetable oils and carbon dioxide [Paper presentation]. Catalysis Applied to Biomass Toward sustainable processes and chemicals (CaBiomass), Compiègne, France.

Alves, M., Méreau, R., Grignard, B., Cramail, H., Jérôme, C., & Tassaing, T. (2014). Valorisation du CO2 et d'huiles végétales pour la stynthèse organocatalytique de carbonates cycliques [Paper presentation]. Journées Francophones des Jeunes Physico-Chimistes (JFJPC), Dammarie--Les-Lys, France.

Grignard, B., Calberg, C., Detrembleur, C., Heinrichs, B., Jérôme, C., & Gilbert, B. (04 August 2013). Toward the synthesis of cyclic carbonate by chemical fixation of carbon dioxide onto epoxides, a kinetic study by Raman spectroscopy under pressure [Poster presentation]. International Conference on Green and Sustainable Chemistry (GSC), Nottingham, United Kingdom.

Clement, B., Grignard, B., Koole, L., Lecomte, P., & Jérôme, C. (15 November 2012). Synthesis of new biomimetic and biodegradable polymers for clinical use [Paper presentation]. Zing conferences "Polymers: From Biomedical Applications to Energy", Xcaret, Mexico.

Alaimo, D., Grignard, B., Fustin, C.-A., Gohy, J.-F., & Jérôme, C. (14 November 2012). Synthesis in scCO2 of nano-hydrogels for proteins delivery [Paper presentation]. Zing conferences "Polymers: From Biomedical Applications to Energy", Xcaret, Mexico.

Boyère, C., Favrelle, A., Grignard, B., Paquot, M., Boury, F., Jérôme, C., & Debuigne, A. (11 October 2012). Synthesis of highly porous matrices by CO2-in-water emulsion polymerization stabilized with new glycosurfactants [Paper presentation]. Club Emulsion 2012, Brussels, Belgium.

Boyère, C., Favrelle, A., Grignard, B., Léonard, A., Pirard, J.-P., Paquot, M., Jérôme, C., & Debuigne, A. (10 September 2012). Use of new surface active carbohydrate esters for the synthesis of polyhipes in supercritical CO2 [Poster presentation]. Journée du département de Chimie de l'Université de Liège, Liège, Belgium.

Clement, B., Grignard, B., Lecomte, P., & Jérôme, C. (10 May 2012). Synthesis of new biomimetic biodegradable materials for clinical use [Poster presentation]. Belgian Polymer Group (BPG) annual meeting 2012, Blankenberge, Belgium.

Alaimo, D., Beigbeder, A., Dubois, P., Broze, G., Grignard, B., & Jérôme, C. (29 April 2011). New fluorinated surfactant for nanogels preparation in supercritical CO2 [Poster presentation]. Journée de l'école doctorale thématique CHIM, Liège, Belgium.

Alaimo, D., Beigbeder, A., Dubois, P., Broze, G., Grignard, B., & Jérôme, C. (29 November 2010). New fluorinated surfactants for nanogels preparation in supercritical CO2 [Poster presentation]. PAI P6/27 Annual Meeting, Brussels, Belgium.

Alexandre, M., Naveau, E., Grignard, B., Raquez, J.-M., Dubois, P., & Jérôme, C. (29 November 2010). Supercritical carbon dioxide as a powerful medium for layered silicate organomodification and new polymer/clay masterbatches preparation [Poster presentation]. PAI P6/27 Annual Meeting, Brussels, Belgium.

Riva, R., Schmeits, S., Croisier, F., Lussis, P., Grignard, B., Lecomte, P., & Jérôme, C. (13 July 2010). Contribution of "click chemistry" to the macromolecular engineering of aliphatic polyesters [Poster presentation]. MACRO 2010, 43rde IUPAC World Polymer Congress, Polymer Science in the Service of Society, Glasgow, United Kingdom.

Grignard, B., Vaillant, A., De Coninck, J., & Jérôme, C. (14 December 2009). Superhydrophobic surfaces by electrospinning of polymer mixtures [Poster presentation]. PAI P6/27 Annual Meeting, Leuven, Belgium.

Grignard, B., Schmeits, S., Riva, R., Lecomte, P., Detrembleur, C., & Jérôme, C. (16 November 2009). Functional aliphatic polyesters by click chemistry in supercritical carbon dioxide [Paper presentation]. Workshop on Supercritical Fluids Processing of Biopolymers and Biomedical Materials, Funchal (Madeira), Portugal.

Grignard, B., Calberg, C., Jérôme, C., & Detrembleur, C. (17 September 2009). New perfulorinated macroligand for the implementation of dispersion atom transfer radical polymerization in sc CO2 [Poster presentation]. Meeting on Controlled Radical Polymerization (CRP Meeting 2009) "Controlled/Living Radical Polymerizations: Latest trends in Synthesis, Characterization and Industrial Applications", Houffalize, Belgium.

Grignard, B., Gigmes, D., Jérôme, C., & Detrembleur, C. (17 September 2009). In situ formation of stabilizers for the implementation of dispersion nitroxide mediated polymerization of MMA in supercritical carbon dioxide [Poster presentation]. Meeting on Controlled Radical Polymerization (CRP Meeting 2009) "Controlled/Living Radical Polymerizations: Latest trends in Synthesis, Characterization and Industrial Applications", Houffalize, Belgium.

Lecomte, P., Riva, R., Schmeits, S., Croisier, F., Grignard, B., Jérôme, R., & Jérôme, C. (03 June 2009). New developments in the functionalization of aliphatic polyesters by "click" copper-catalyzed azide-alkyne cycloaddition [Paper presentation]. EUPOC2009, EPF Europolymer Conference, "Click" - Methods in Polymer and Materials Science, Gargnano, Italy.

Grignard, B., Calberg, C., Jérôme, C., & Detrembleur, C. (19 May 2009). Preparation of living polymer microspheres by dispersion atom transfer radical polymerization in scCO2 using fluorinated macroligands [Poster presentation]. 9th International Symposium on Supercritical Fluids (ISSF 2009) : New Trends in Supercritical Fluids ; Energy, Materials, Processing, Arcachon, France.

Grignard, B., Schmeits, S., Riva, R., Lecomte, P., Detrembleur, C., & Jérôme, C. (19 May 2009). Click reaction in supercritical carbon dioxide: towards the synthesis of functional polymers in a green medium [Paper presentation]. 9th International Symposium on Supercritical Fluids (ISSF 2009) : New Trends in Supercritical Fluids ; Energy, Materials, Processing, Arcachon, France.

Grignard, B., Gigmes, D., Jérôme, C., & Detrembleur, C. (14 May 2009). Dispersion nitroxide mediated polymerization of MMA in supercritical carbon dioxide [Poster presentation]. Belgian Polymer Group (BPG) annual meeting 2009, Houffalize, Belgium.

Grignard, B., Schmeits, S., Riva, R., Detrembleur, C., Lecomte, P., & Jérôme, C. (14 May 2009). Functionalization of aliphatic polyesters by “click chemistry” in supercritical carbon dioxide [Poster presentation]. Belgian Polymer Group (BPG) annual meeting 2009, Houffalize, Belgium.

Aqil, A., Grignard, B., Croisier, F., Pirard, R., & Jérôme, C. (28 November 2008). Polymer membrane by electrospinning [Poster presentation]. PAI P6/27 Annual Meeting, Leuven, Belgium.

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., & Detrembleur, C. (28 November 2008). Design of perfluorinated macroligand for the implementation of atom transfer radical polymerization in supercritical carbon dioxide [Paper presentation]. PAI P6/27 Annual Meeting, Leuven, Belgium.

Grignard, B., Urbanczyk, L., Stassin, F., Calberg, C., Detrembleur, C., & Jérôme, C. (02 June 2008). Supercritical carbon dioxide, a tool for the dispersion ROP of lactone and PCL foaming: Part A [Poster presentation]. Workshop on biomacromolecules, Renewable, Degradable and Biomedical Polymers, Stockholm, Sweden.

Grignard, B., Vaillant, A., De Coninck, J., & Jérôme, C. (22 May 2008). Superhydrophobic surfaces by electrospinning of polymer mixtures [Poster presentation]. Belgian Polymer Group (BPG) annual meeting 2008, De Haan, Belgium.

Grignard, B., Jérôme, C., Calberg, C., Jérôme, R., Wang, W., Howdle, S., & Detrembleur, C. (05 May 2008). New perfluorinated macroligand for the implementation of Atom Transfer Radical Polymerization in supercritical carbon dioxide [Paper presentation]. 11th European Meeting on Supercritical Fluids New Perspectives in Supercritical Fluids: Nanoscience, Materials and Processing, Barcelona, Spain.

Grignard, B., Calberg, C., Jérôme, C., Wang, W., Howdle, S., Jérôme, R., & Detrembleur, C. (31 August 2007). Polymers synthesis in sc CO2: dispersion ROP of ε-caprolactone and dispersion ATRP of vinyl monomers [Poster presentation]. Polymers: Last achievements and prospects, in honour of Professor Jérôme, Liège, Belgium.

Sorlier, P., Grignard, B., Mitu, A., Nedecheva, A., Detrembleur, C., Jérôme, R., & Jérôme, C. (31 August 2007). Electrospinning and nanofibers [Poster presentation]. Polymers: Last achievements and prospects, in honour of Professor Jérôme, Liège, Belgium.

Grignard, B., Jérôme, C., Calberg, C., Detrembleur, C., & Jérôme, R. (24 May 2007). Implementation of atom transfer radical polymerization in supercritical carbon dioxide [Paper presentation]. Belgian Polymer Group (BPG) annual meeting 2007, Houffalize, Belgium.

Urbanczyk, L., Grignard, B., Stassin, F., Calberg, C., & Jérôme, R. (01 June 2005). Synthesis of polymer nanocomposites and microspheres in supercritical carbon CO2 [Poster presentation]. Advanced nanomaterials for biofunctional surfaces, Liège, Belgium.

Urbanczyk, L., Grignard, B., Stassin, F., Calberg, C., & Jérôme, R. (01 June 2005). Synthesis and foaming of polymer nanocomposites and microspheres in supercritical CO2 [Poster presentation]. Advanced nanomaterials for biofunctional surfaces, Liège, Belgium.

Grignard, B., Claes, M., Sciannamea, V., Koulic, C., & Jérôme, R. (16 May 2003). Synthesis of end functional (co)polymers, precursors of triblock copolymers by controlled radical polymerization [Poster presentation]. Recent Progress in Macromolecular Chemistry, Liège, Belgium.

Theses and dissertations

Doctoral thesis

Grignard, B. (2007). Design of perfluorinated macroligands for the implementation of atom transfer radical polymerization in supercritical carbon dioxide [Doctoral thesis, ULiège - Université de Liège]. ORBi-University of Liège. https://orbi.uliege.be/handle/2268/21588

Other publications and communications

Articles in scientific journals without peer reviewing

Grignard, B. (2019). Le CO2, un déchet au service de l'innovation. Bulletin de la Société Royale des Sciences de Liège, 88, 64 - 72. doi:10.25518/0037-9565.9205

Speeches and writings for a general audience

Conferences given outside the academic context

Léonard, G., Evrard, B., Grignard, B., & Courard, L. (2019). Plein gaz : enjeux et perspectives de la valorisation du CO2 [Paper presentation]. Rencontre Liège Creative - Réutilisation du CO2, Liège, Belgium.