CO2-rich groundwater; Geophysics; Induced polarisation; Mineral water; Prospection
Résumé :
[en] CO2-rich mineral groundwaters are of great economic and touristic interest but their origin and circulation paths in the underground are often poorly understood. A deeper understanding of the system plumbery and the development of non—to minimally—invasive near-surface geophysical methods for the prospection of potential productive areas is therefore of great interest to manage future supply. The objective of this contribution is to assess the ability of the time-domain induced polarization (TDIP) method, combined with the electrical resistivity tomography (ERT) method, to make the distinction between CO2-rich groundwater from non-gaseous groundwater. Three combined ERT/TDIP tomographies were performed above known uplift zones in the south-east of Belgium where thousands of CO2-rich groundwater springs exist. On all profiles, important contrasts in both electrical resistivity and chargeability distributions were observed in the vicinity of the upflow zone, also reflected in the normalized chargeability sections computed from the measured data. Low resistivity vertical anomalies extending in depth were interpreted as a saturated fracture network enabling the upflow of deep groundwater to the surface. High chargeability anomalies appearing directly close to the CO2-rich groundwater springs were inferred to metallic oxides and hydroxides precipitation in the upper part of the aquifer, linked to pressure decrease and changing redox conditions in the up-flowing groundwater approaching the land surface. The combined interpretation of electrical resistivity and induced polarization datasets provides a very promising method for a robust prospection of CO2-rich groundwater.
Dewandel, B.; Alazard, M.; Lachassagne, P.; Bailly-Compte, V.; Coueffe, R.; Grataloup, S.; Ladouche, B. Respective roles of the weathering profile and the tectonic fractures in the structures and functioning of crustalline thermo-mineral carbo-gaseous aquifers. J. Hydrol. 2017, 547, 690-707.
Marechal, J.; Lachassagne, P.; Ladouche, B.; Dewandel, B.; Lanini, S.; Strat, P.L.; Petelet-Giraud, E. Structure and hydrogeochemical functioning of a sparkling natural mineral water system determined using a multidisciplinary approach: A case study from southern France. Hydrogeol. J. 2014, 22, 47-68.
Goepel, A.; Lonschiniski, M.; Viereck, L.; Buchel, G.; Kukowski, N. Volcano-tectonic structures and CO2-degassing patterns in the Laccher See basin, Germany. Int. J. Earth Sci. 2015, 104, 1483-1495.
Lesniak, P.M. Origin of carbon dioxide and evolution of CO2-rich waters in the West Carapathians, Poland. Acta Geol. Pol. 1998, 48, 343-366.
Grassa, F.; Capasso, G.; Favara, R.; Inguaggiato, S. Chemical and isotopic composition of waters and dissolved gases in some thermal springs of Sicily and adjacent volcanic islands, Italy. Pure Appl. Geophys. 2006, 163, 781-807.
Carreira, P.; Marques, J.; Carvalho, M.; Nunes, D.; da Silva, M.A. Carbon isotopes and geochemical processes in CO2-rich cold mineral water, N-Portugal. Environ. Earth Sci. 2014, 71, 2941-2953.
Tassi, F.; Vaselli, O.; Moratti, G.; Piccardi, L.; Minissle, A.; Poreda, R.; Huertas, A.D.; Bendkik, A.; Chenakeb, M.; Tedesco, D. Fluid geochemistry versus tectonic setting: The case study of Morocco. Geol. Soc. Lond. Spec. Publ. 2006, 262, 131-145.
Shugg, A. Hepburn Spa: Cold carbonated mineral waters of Central Victoria, South Eastern Australia. Environ. Geol. 2008, 58, 1663-1673.
Choi, H.; Woo, N.C. Natural analogue monitoring to estimate the hydrochemical change of groundwater by the carboating process from the introduction of CO2. J. Hydrol. 2018, 562, 318-334.
Honnegger, J.; Gadalia, A. Exploitation des eaux minérales carbo-gazeuses. Houille Blanche 1995, 2, 106-110.
Rubin, Y.; Hubbard, S. Hydrogeophysics; Springer Science & Business Media: Cham, Switzerland, 2006; Volume 50.
Gao, Q.; Shang, Y.; Hasan, M.; Jin, W.; Yang, P. Evaluation of a weathered rock aquifer using ERT method in South Guangdong, China. Water 2018, 10, 293.
Robinson, J.; Slater, L.; Johnson, T.; Shapiro, A.; Tiedeman, C.; Ntarlagiannis, D.; Lane, J. Imaging pathways in fractured rock using three-dimensional electrical resistivity tomography. Groundwater 2016, 5, 186-201.
Robert, T.; Dassargues, A.; Brouyère, S.; Kaufmann, O.; Hallet, V.; Nguyen, F. Assessing the contribution of electrical resistivity tomography (ERT) and self-potential (SP) methods for a water well drilling program in fractured/karstified limestones. J. Appl. Geophys. 2011, 75, 42-53.
Ball, L.B.; Ge, S.; Caine, J.S.; Revil, A.; Jardani, A. Constraining fault-zone hydrogeology through integrated hydrological and geoelectrical analysis. Hydrogeol. J. 2010, 18, 1057-1067.
Yadav, G.; Singh, S. Integrated resistivity surveys for delineation of fractures for groundwater exploration in hard rock areas. J. Appl. Geophys. 2007, 62, 301-312.
Nguyen, F.; Sand, D.; Jongmans, S.G.; Pirard, E.; Loke, M. Image processing of 2D resistivity data for imaging faults. J. Appl. Geophys. 2005, 57, 260-277.
Binley, A.; Kemna, A. DC resistivity and induced polarization methods. In Hydrogeophysics; Springer: Cham, Switzerland, 2005; pp. 129-156.
Revil, A.; Aal, G.A.; Atekwana, E.; Mao, D.; Florsh, N. Induced polarization response of porous media with metallic particles-2: Comparison with a broad database of experimental data. Geophysics 2015, 80, 539-552.
Mao, D.; Revil, A. Induced polarization response of porous media with metallic particles-Part 3: A new approach to time-domain induced polarization tomography. Geophysics 2016, 81, 345-357.
Weller, A.; Slater, L.; Nordsiek, S. On the relationship between induced polarization and surface conductivity: Implications for petrophysical interpretation of electrical measurements. Geophysics 2013, 78, 315-325.
Chelidze, T.; Gueguen, Y. Electrical spectroscopy of porous rocks: A review-I. Theoretical models. Geophys. J. Int. 1999, 137, 1-15.
Bleil, D. Induced polarization: A method of geophysical prospecting. Geophysics 1953, 18, 636-661.
Mansoor, N.; Slater, L. On the relationship between iron concentration and induced polarization in marsh soils. Geophysics 2006, 72, 1-5.
Moreira, C.; Borges, M.; Vieira, G.; Filho, W.; Montanheiro, M. Geological and geophysical data intergration for delimitation of mineralized areas in a supergene manganese deposits. Geofis. Int. 2012, 53, 403-416.
Srigutomo, W.; Trimadona.; Pratomo, P. 2D Resistivity and Induced Polarization Measurement for Manganese Ore Exploration. J. Phys. Conf. Ser. 2016, 739, 012138.
Carlson, N.R.; Hare, J.L.; Zonge, K.L. Buried landfill delineation with induced polarization: Progress and problems. In Proceedings of the SAGEEP, 14th EEGS Symposium on the Application of Geophysics to Engineering and Environmental Problems, Denver, CO, USA, 4-7 March 2001; Volume 20.
Kemna, A.; Binley, A.; Slater, L. Crosshole IP imaging for engineering and environmental applications. Geophysics 2004, 69, 97-107.
Gazoty, A.; Fiandaca, G.; Pedersen, J.; Auken, E.; Christiansen, A. Mapping of landfills using time-domain spectral induced polarization data: The Eskelund case study. Surf. Geophys. 2012, 10, 575-586.
Dafflon, B.;Wu, Y.; Hubbard, S.; Birkholzer, J.; Daley, T.; Pugh, J.; Trautz, R. Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods. Environ. Sci. Technol. 2012, 47, 314-321.
Kremer, T.; Schmutz, M.; Agrinier, P.; Maineult, A. Laboratory monitoring of CO2 injection in saturated silica and carbonate sands using spectral induced polarization. Geophys. J. Int. 2016, 207, 1258-1272.
Aizebeokhai, A.; Oyeyemi, K.; Joel, E. Electrical resistivity and induced-polarization imaging for groundwater exploration. In Proceedings of the SEG Technical Program Expanded Abstracts, Dallas, TX, USA, 16-21 October 2016; Society of Exploration Geophysicists: Houston, TX, USA, 2016; pp. 2487-2491.
Chrindja, F.J.; Dahlin, T.; Steinbruch, F. Reconstructing the formation of a costal aquifer in Nampula province, Mozambique, from ERT and IP methods for water prospection. Environ. Earth Sci. 2017, 76, 36.
Levy, L.; Maurya, P.; Byrdina, S.; Vandemeulebrouck, J.; Sigmundsson, F.; Arnason, K.; Labazuy, P. Electrical Resistivity Tomography and Time-Domain Induced Polarization field investigations of geothermal areas at Krafla, Iceland: comparison to borehole and laboratory frequency-domain electrical observations. Geophys. J. Int. 2019, 218, 1469-1489.
Wollast, R.; Wollast, A. Etude géochimique des eaux carbogazeuses de la région de Stoumont. Les Eaux Souterraines en WALLONIE, Bilan et Perspectives-ESO 87; Région Wallonne of Belgium: Namur, Belgium, 1987.
Oldenburg, D.; Li, Y. Inversion for applied geophysics: A tutorial. Investig. Geophys. 2005, 13, 89-150.
Airo, M. Geophysical signatures of mineral deposit types. Geol. Surv. Finl. Spec. Pap. 2015, 58, 9-70.
King, A.; Milkereit, B. Review of geophysical technology for Ni-Cu-PGE deposits. In Proceedings of Fifth Decennial International Conference on Mineral Exploration, Toronto, ON, Canada, 9-12 September 2007; Decennial Mineral Exploration Conferences: Toronto, ON, Canada, 2007; Volume 7, pp. 647-665.
Vanbrabant, Y.; Braun, J.; Jongmans, D. Models of passive margin inversion: Implications for the Rhenohercynian fold-and-thrust belt, Belgium and Germany. Earth Planet. Sci. Lett. 2002, 202, 15-29.
Hance, L.; Dejonghe, L.; Ghysel, P.; Laloux, M.; Mansy, J. Influence of heterogeneous lithostructural layering on orogenic deformation in the Variscan Front Zone (eastern Belgium). Tectonophysics 1999, 309, 161-177.
Goemaere, E.; Demarque, S.; Dreeseen, R.; Declercq, P.Y. The Geological and Cultural Heritage of the Caledonien Stavelot-Venn Massif, Belgium. Geoheritage 2016, 8, 211-233.
Belanger, I.; Delaby, S.; Delcambre, B.; Ghysel, P.; Hennebert, M.; Laloux, M.; Marion, J.; Mottequin, B.; Pingot, J. Redéfinition des unités structurales du front varisque utilisées dans le cadre de la nouvelle Carte Géologique de Wallonie (Belgique). Geol. Belg. 2012, 15, 169-175.
Herbosch, A.; Liégeois, J.P.; Pin, C. Coticules of the Belgian type area (Stavelot-Venn Massif): Limy turbidites within the nascent Rheic oceanic basin. Earth-Sci. Rev. 2016, 159, 186-214.
Geukens, F. Strike skip deformation des deux cotés du Graben de Malmédy. Ann. De La Société Géologique De Belg. 1995, 118, 139-146.
Debbaut, V.; Cajot, O.; Ruthy, I.; Dassargues, A.; Hanson, A.; Bouezmarni, M. Aquifères de l'Ardenne; Academia Press: Gent, Belgium, 2014.
Blondel, A. Développement des méThodes géOphysiques Électriques pour la Caractérisation des Sites et Sols Pollués aux Hydrocarbures. Ph. D. Thesis, Ecole Doctorale Montaigne-Humanités, Pessac, France, 2014.
Schön, J. Physical Properties of Rocks: Fundamentals and Principles of Petrophysics; Elsevier: Amsterdam, The Netherlands, 1996; Volume 65.
Slater, L.; Lesmes, D. Electrical-hydraulic relationships observed for unconsolidated sediments. Water Resour. Res. 2002, 38, 31-1.
Aster, R.; Borchers, B.; Thurber, C. Parameter Estimation and INVERSE Problems; Elsevier: Amsterdam, The Netherlands, 2018.
Binley, A.; Slater, L.; Fukes, M.; Cassiani, G. Relationship between spectral induced polarization and hydraulic properties of saturated and unsaturated sandstone. Water Resour. Res. 2005, 41, 12.
Gazoty, A.; Fiandaca, G.; Pedersen, J.; Auken, E.; Christiansen, A. Data repeatability and acquisition techniques for time-domain spectral induced polarization. Surf. Geophys. 2013, 11, 391-406.
Loke, M.; Kuras, O.; Chambers, J.; Rucker, D.; Wilkinson, P. Instrumentation, Electrical Resistivity. In Encyclopedia of Solid Earth Geophysics; Gupta, H.K., Ed.; Springer International Publishing: Cham, Switzerland, 2020; pp. 1-7.
Dahlin, T.; Zhou, B. Multiple-gradient array measurements for multichannel 2D resistivity imaging. Surf. Geophys. 2006, 4, 113-123.
Aizebeokhai, A.; Oyeyemi, K. The use of the multiple-gradient array for geoelectrical resistivity and induced polarization imaging. J. Appl. Geophys. 2014, 111, 364-376.
Dahlin, T.; Leroux, V.; Nissen, J. Measuring techniques in induced polarisation imaging. J. Appl. Geophys. 2002, 50, 279-298.
Loke, M.; Barker, R. Rapid least-squares inversion of apparent resistivity pseudosections by a quasi-Newton method. Geophys. Prospect. 1996, 44, 131-152.
Loke, M.; Chambers, J.; Ogilvy, R. Inversion of 2D spectral induced polarization imaging data. Geophys. Prospect. 2006, 54, 287-301.
Caterina, D.; Beaujean, J.; Robert, T.; Nguyen, F. A comparison study of different image appraisal tools for electrical resistivity tomogrphy. Surf. Geophys. 2013, 11, 639-657.
MacNeill, J. Electrical Conductivity of Soils and Rocks; Geonics Limited: Mississauga, ON, Canada, 1980.
Portal, A.; Belle, P.; Mathieu, F.; Lachassagne, P.; Brisset, N. Identification and Characterization of Hard Rocks Weathering Profile by Electrical Resistivity Imaging. In Proceedings of the 23rd European Meeting of Environmental and Engineering Geophysics. European Association of Geoscientists & Engineers, Malmo, Sweden, 3-7 September 2017; Volume 2017, pp. 1-5.
Lamberty, P.; Geukens, F.; Marion, J. Notice explicative de la carte géologique Stavelot-Malmédy (50 5-6). Available online: https://orbi.uliege.be/handle/2268/207547 (accessed on 10 May 2020).
Modelska, M.; Buczyński, S.; Blachowicz, M.; Heidemann, M.; Grzeda, O.; Karkoszka, L. The Mofetta Tylicz-an example of carbonated water springs in the area of Tylicz (Beskid Sadecki, the Carpathians). Geosci. Rec. 2015, 1, 27-33.
Operacz, A.; Wasik, E.; Hajduga, M.; Chmielowski, K. Therapeutic water in the Poprad Valley-the newest development in the polish outer Carpathians. Pol. J. Environ. Stud. 2018, 27, 1207-1217.
Jeong, C.H.; Kim, H.J.; Lee, S.Y. Hydrochemistry and genesis of CO2-rich springs from Mesozoic granitoids and their adjacent rocks in South Korea. Geochem. J. 2005, 39, 517-530.
Chae, G.; Yu, S.; Jo, M.; Choi, B.Y.; Kim, T.; Koh, D.C.; Yun, Y.Y.; Yun, S.T.; Kim, J.C. Monitoring of CO2-rich waters with low pH and low EC: An analogue study of CO2 leakage intro into shallow aquifers. Environ. Eath Sci. 2016, 75, 15.
Langmuir, D. Aqueous Environmental Geochemistry; Prentice Hall: Upper Saddle River, NJ, USA, 1997.
Aal, G.A.; Atekwana, E.; Revil, A. Geophysical signatures of disseminated iron minerals: A proxy for understanding subsurface biophysicochemical processes. J. Geophys. Res. Biogeosci. 2014, 119, 1831-1849.
Slater, L.; Choi, J.; Wu, Y. Electrical properties of iron-sand columns: Implications for induced polarization investigation and performance monitoring of iron-wall barriers. Geophysics 2005, 70, G87-G94.
Evrard, M.; Dumont, G.; Hermans, T.; Chouteau, M.; Francis, O.; Pirard, E.; Nguyen, F. Geophysical Investigation of the Pb-Zn Deposit of Lontzen-Poppelsberg, Belgium. Minerals 2018, 8, 233.
Moreira, C.; Borssatto, K.; Ilha, L.; Santos, S.; Rosa, F. Geophysical modeling in gold deposit through DC Resistivity and Induced Polarization methods. REM-Int. Eng. J. 2016, 69, 293-299.
Okay, G.; Cosenza, P.; Ghorbani, A.; Camerlynck, C.; Cabrera, J.; Florsch, N.; Revil, A. Localization and characterization of cracks in clay-rocks using frequency and time-domain induced polarization. Geophys. Prospect. 2013, 61, 134-152.
Krahenbuhl, R.; Hitzman, M. Geophysical modeling of two willemite deposits, Vazante (Brazil) and Beltana (Australia). In SEG Technical Program Expanded Abstracts 2004; Society of Exploration Geophysicists: Houston, TX, USA, 2004; pp. 1187-1190.
Dakir, I.; Benamara, A.; Aassoumi, H.; Ouallali, A.; Bahammou, Y.A. Application of Induced Polarization and Resistivity to the Determination of the Location of Metalliferous Veins in the Taroucht and Tabesbaste Areas (Eastern Anti-Atlas, Morocco). Int. J. Geophys. 2019, 2019, 1-11.
Pardo, O.; Gretta, C.; Alexander, E.; Iraida, M.; Pintor, B. Geophysical exploration of disseminated and stockwork deposits associated with plutonic intrusive rock: A case study on the eastern flank of Colombia's western cordillera. Earth Sci. Res. J. 2012, 16, 11-23.
Sultan, S.; Mansour, S.; Santos, F.; Helaly, A. Geophysical exploration for gold and associated minerals, case study: Wadi El Beida area, South Eastern Desert, Egypt. J. Geophys. Eng. 2009, 6, 345-356.
Azis, A.; Zamhuri, M.; Rais, M.; Aswad, S.; Patiung, O.; Sudianto, Y. Identify the Distribution of Galena using Induced Polarization and Resistivity Methods in central of Lombok, West Nusa Tenggara. In Proceedings of the IOP Conference Series: Earth and Environmental Science, Makassar, Indonesia, 1-2 November 2018; IOP Publishing: Bristol, UK, 2019; Volume 279.
Amaya, A.G.; Dahlin, T.; Barmen, G.; Rosberg, J.E. Electrical resistivity tomography and induced polarization for mapping the subsurface of alluvial fans: A case study in Punata (Bolivia). Geosciences 2016, 6, 51.
Yusof, M.A.A.; Ismail, N.; Muztaza, N. The Application of 2D Resistivity and Induced Polarization Methods for Slope Study at Penang Island, Malaysia. In Proceedings of the SEGJ 136th (Spring) Conference, Tokyo, Japan, 5-7 June 2017; The Society of Exploration Geophysicists of Japan: Tokyo, Japan, 2017.
Dahlin, T. Application of Resistivity-IP to Mapping of Groundwater Contamination and Buried Waste; Geophysical Association of Ireland: Dublin, Ireland, 2012; p. 6.
Leroux, V.; Dahlin, T.; Svensson, M. Dense resistivity and induced polarization profiling for a landfill restoration project at Härlöv, Southern Sweden. Waste Manag. Res. 2007, 25, 49-60.
Dahlin, T.; Rosqvist, H.; Leroux, V. Resistivity-IPmapping for landfill applications. First Break 2010, 28, 101-105.
Johansson, B.; Jones, S.; Dahlin, T.; Flyhammar, P. Comparisons of 2D-and 3D-inverted resistivity data as well as of resistivity-and IP-surveys on a landfill. In Proceedings of the Near Surface 2007-13th EAGE European Meeting of Environmental and Engineering Geophysics, Istanbul, Turkey, 3-5 September 2007.
Santos, F.A.M.; Almeida, E.P.; Castro, R.; Nolasco, R.; Mendes-Victor, L. A hydrogeological investigation using EM34 and SP surveys. Earth Planets Space 2002, 54, 655-662.
Marques, J.; Santos, M.F.; Graça, R.; Castro, R.; Aires-Barros, L.; Victor, L.M. A geochemical and geophysical approach to derive a conceptual circulation model of CO 2-rich mineral waters: A case study of Vilarelho da Raia, northern Portugal. Hydrogeol. J. 2001, 9, 584-596.