References of "Brouyère, Serge"
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See detailHeat tracer test in an alluvial aquifer: field experiment and inverse modelling
Klepikova, Maria; Wildemeersch, Samuel; Jamin, Pierre ULiege et al

Poster (2016, April 20)

Using heat as an active tracer for aquifer characterization is a topic of increasing interest. In this study, we investigate the potential of using heat tracer tests for characterization of a shallow ... [more ▼]

Using heat as an active tracer for aquifer characterization is a topic of increasing interest. In this study, we investigate the potential of using heat tracer tests for characterization of a shallow alluvial aquifer. A thermal tracer test was conducted in the alluvial aquifer of the Meuse River, Belgium. The tracing experiment consisted in simultaneously injecting heated water and a dye tracer in a piezometer and monitoring the evolution of groundwater temperature and tracer concentration in the recovery well and in monitoring wells. To get insights in the 3D characteristics of the heat transport mechanisms, temperature data from a large number of observation wells distributed throughout the field site (space-filling arrangement) were used. Temperature breakthrough curves in observation wells are contrasted with what would be expected in an ideal layered aquifer. They reveal strongly unequal lateral and vertical components of the transport mechanisms. The observed complex behavior of the heat plume was explained by the groundwater flow gradient on the site and heterogeneity of hydraulic conductivity field. Moreover, due to high injection temperatures during the field experiment a temperature-induced fluid density effect on heat transport occurred. By using a flow and heat transport numerical model with variable density coupled with the pilot point inverse approach, main preferential flow paths were delineated. [less ▲]

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See detailRessources en eau au Bénin: Problématique, enjeux et défis d’une gestion durable
Tossou, Yao ULiege; Orban, Philippe ULiege; Ruthy, Ingrid ULiege et al

Scientific conference (2016, March 12)

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See detailCombining cross - hole geophysical and vadose zone monitoring systems for vadose zone characterization at industrial contaminated sites
Fernandez de Vera, Natalia; Beaujean, Jean; Jamin, Pierre ULiege et al

in Hydrology & Earth System Sciences Discussions (2016)

Water flow and solute transport through a fractured vadose zone underneath an industrial contaminated site in Belgium were studied with a new methodological concept. The Vadose Zone Experimental Setup ... [more ▼]

Water flow and solute transport through a fractured vadose zone underneath an industrial contaminated site in Belgium were studied with a new methodological concept. The Vadose Zone Experimental Setup (VZES) combines a vadose zone monitoring system (VMS) with cross-borehole geophysics. The VMS provides continuous chemical and hydraulic information at multiple depths in the vadose zone. When combining such information with multidirectional subsurface imaging from geophysical measurements, flow and transport can be characterized at a scale that covers the spatial variability of the subsurface. The setup was installed on site and monitoring was carried out under natural recharge conditions. Results reveal quick rises in water content as a response to rainfall events in the upper and intermediate part of the vadose zone (down to 3.65m depth). Macropore, micropore, matrix and preferential flow mechanisms are identified at these depth ranges. At greater depths, flow dynamics is slower and dominated by matrix flow. The governance of water flow mechanisms at different directions is controlled by the heterogeneous distribution of geological materials. Results from sampled waters across the vadose zone reveal that the chemistry of water collected from matrix is different from that collected from fractures. In addition, analysis of heavy metals indicates that Ni is leaching across the vadose zone, and its release might be a consequence of pyrite oxidation from backfilled materials. Results obtained from VZES indicate that the combination of different techniques providing in situ quantitative and qualitative information improves conceptual models of flow and transport in a heterogeneous subsurface. [less ▲]

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See detailUse of dual carbon-chlorine isotope analysis to assess the degradation pathways of 1,1,1-trichloroethane in groundwater
Palau, Jordi; Jamin, Pierre ULiege; Badin, Alice et al

in Water Research (2016)

Compound-specific isotope analysis (CSIA) is a powerful tool to track contaminant fate in groundwater. However, the application of CSIA to chlorinated ethanes has received little attention so far. These ... [more ▼]

Compound-specific isotope analysis (CSIA) is a powerful tool to track contaminant fate in groundwater. However, the application of CSIA to chlorinated ethanes has received little attention so far. These compounds are toxic and prevalent groundwater contaminants of environmental concern. The high susceptibility of chlorinated ethanes like 1,1,1-trichloroethane (1,1,1-TCA) to be transformed via different competing pathways (biotic and abiotic) complicates the assessment of their fate in the subsurface. In this study, the use of a dual C-Cl isotope approach to identify the active degradation pathways of 1,1,1-TCA is evaluated for the first time in an aerobic aquifer impacted by 1,1,1-TCA and trichloroethylene (TCE) with concentrations of up to 20 mg/L and 3.4 mg/L, respectively. The reaction-specific dual carbon-chlorine (C-Cl) isotope trends determined in a recent laboratory study illustrated the potential of a dual isotope approach to identify contaminant degradation pathways of 1,1,1-TCA. Compared to the dual isotope slopes (Δδ13C/Δδ37Cl) previously determined in the laboratory for dehydrohalogenation / hydrolysis (DH/HY, 0.33 ± 0.04) and oxidation by persulfate (∞), the slope determined from field samples (0.6 ± 0.2, r2 = 0.75) is closer to the one observed for DH/HY, pointing to DH/HY as the predominant degradation pathway of 1,1,1-TCA in the aquifer. The observed deviation could be explained by a minor contribution of additional degradation processes. This result, along with the little degradation of TCE determined from isotope measurements, confirmed that 1,1,1-TCA is the main source of the 1,1-dichlorethylene (1,1-DCE) detected in the aquifer with concentrations of up to 10 mg/L. This study demonstrates that a dual C-Cl isotope approach can strongly improve the qualitative and quantitative assessment of 1,1,1-TCA degradation processes in the field. [less ▲]

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See detailHow heterogeneity of the K-field influences a heat plume in a shallow alluvial aquifer: responses from a heat tracer test
Klepikova, Maria; Jamin, Pierre ULiege; Orban, Philippe ULiege et al

in Abstract book (2016, January 26)

Simultaneous solute and heat tracer test provides essential information for a reliable assessment of low temperature geothermal systems. The actual efficiency of ‘open systems’, including heat storage ... [more ▼]

Simultaneous solute and heat tracer test provides essential information for a reliable assessment of low temperature geothermal systems. The actual efficiency of ‘open systems’, including heat storage projects, is strongly affected by the heterogeneity of the hydraulic conductivity field (K-field). It could be also useful for assessing the cumulative impacts of numerous projects in urban areas on the groundwater resources. Using field data from a solute and heat tracer test conducted in the alluvial aquifer of the Meuse River (Belgium), an inverse problem of parameter estimation is solved. The tracing experiment consisted in simultaneously injecting heated water and a dye tracer in a piezometer and monitoring the evolution of groundwater temperature and tracer concentration in the recovery well and in monitoring wells. To get insights in the 3D characteristics of the heat plume, an arrangement of three transects of observation wells was used. The breakthrough curves measured in the recovery well showed that heat transfer in the alluvial aquifer is slower and more dispersive than solute transport. Recovery is very low for heat while in the same time it is measured as relatively high for the solute tracer. This is due to the fact that heat transport is a thermal diffusion dominated process. For conditions corresponding to high Peclet numbers, the hydraulic conductivity is the primary calibration parameter for predicting heat plume distribution. Heat diffusion is larger than molecular diffusion, implying that exchange between groundwater and the porous medium matrix is far more significant for heat than for solute tracers. [less ▲]

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See detailLe bassin du Triffoy et les eaux souterraines : Exemple de caractérisation des échanges entre nappe et rivière
Briers, Pierre ULiege; Descy, Jean-Pierre; Schmit, Flore et al

in Atlas du Karst Wallon - Bassins versants du Hoyoux et de la Solières (2016)

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See detailHydrogéologie du bassin du Hoyoux
Briers, Pierre ULiege; Jamin, Pierre ULiege; Ruthy, Ingrid ULiege et al

in Atlas du Karst Wallon - Bassins versants du Hoyoux et de la Solières (2016)

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See detailDélivrable D3.3 Bilans hydrogéologiques
Schmit, Flore; Hallet, Vincent; Briers, Pierre ULiege et al

Report (2016)

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See detailHeat tracer and solute tests in an alluvial aquifer: field experiment and inverse modelling
Dassargues, Alain ULiege; Klepikova, Maria; Jamin, Pierre ULiege et al

Poster (2015, December 18)

Using heat as an active tracer in different types of aquifers is a topic of increasing interest. In this study, we investigate the potential interest of using heat tracer tests for characterization of a ... [more ▼]

Using heat as an active tracer in different types of aquifers is a topic of increasing interest. In this study, we investigate the potential interest of using heat tracer tests for characterization of a shallow alluvial aquifer. A thermal tracer test was conducted in the alluvial aquifer of the Meuse River, Belgium. The tracing experiment consisted in simultaneously injecting heated water and a dye tracer in a piezometer and monitoring the evolution of groundwater temperature and tracer concentration in the recovery well and in monitoring wells. To get insights in the 3D characteristics of the heat transport mechanisms the space-filling arrangement of observation wells was used. The breakthrough curves measured in the recovery well showed that heat transfer in the alluvial aquifer is slower and more dispersive than solute transport. Recovery is very low for heat while in the same time it is measured as relatively high for the solute tracer. This is due to the fact that heat diffusion is larger than molecular diffusion, implying that exchange between groundwater and the porous medium matrix is far more significant for heat than for solute tracers. Temperature breakthrough curves in other piezometers are contrasted with what would be expected in an ideal layered aquifer. They reveal strongly unequal lateral and vertical components of the transport mechanisms. The observed complex behavior of the heat plume was explained by the groundwater flow gradient on the site and heterogeneities of hydraulic conductivity field. By using numerical model of heat and flow coupled with pilot points inverse approach main preferential paths were characterized. [less ▲]

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See detailCase study 2: Groundwater – surface water interaction in limestone areas of the GWB BE_Meuse_RWM021 (Belgium)
Brouyère, Serge ULiege; Briers, Pierre ULiege; Schmit, Flore et al

in Hinsby, Klaus; Schutten, Johan; Craig, Matt (Eds.) et al Technical Report on Groundwater Associated Aquatic Ecosystems (2015)

The achievement of good status in groundwater bodies involves meeting a series of conditions, which are defined in the Water Framework Directive (WFD) and, in the case of good chemical status, are given ... [more ▼]

The achievement of good status in groundwater bodies involves meeting a series of conditions, which are defined in the Water Framework Directive (WFD) and, in the case of good chemical status, are given further detail in the Groundwater Directive (GWD). One of these conditions is to ensure that groundwater inputs to associated surface waters do not result in failure to meet the environmental objectives of those waters or result in significant diminution in status/ecological or chemical quality of those waters. GWAAE (Groundwater Associated Aquatic Ecosystems) are those surface water bodies (SWBs), including rivers, standing waters and transitional waters where the surface water ecology and hydrology is dependent on contributions from groundwater in order to meet their environmental objectives under the WFD. These environmental objectives may vary, and therefore the associated environmental quality standards (EQS) or flow/level requirements of GWAAEs may differ between high status and good status SWBs. As noted in the Blueprint for Water, analysis of the first River Basin Management Plans has shown that Member States (MS) have experienced difficulties in understanding the interactions between groundwater and surface water and undertaking the necessary status assessments. This was highlighted in a survey carried out by Working Group Groundwater (WGGW) in 2014/15, which indicated that only half of the MS had assessed quantitative interactions and very few had addressed chemical pressures, including the derivation of threshold values (TVs) that were appropriate to the WFD objectives for GWAAEs. This report aims to further knowledge on what GWAAE are, how they are aligned to WFD processes, and support Member States to properly include the needs of these ecosystems in river basin management planning. The report clarifies the categories of GWAAE and their relative dependence on groundwater and collates current available knowledge and experience via a number of examples and case studies. Terminology and status assessment procedures are explained and pragmatic approaches are proposed which leave some flexibility for MS to adapt to their own specific needs. This technical report, which is not a "guidance document", makes use of and complements existing CIS documents, including existing technical reports on groundwater dependent terrestrial ecosystems (GWDTEs) and Guidance Document 18 (Guidance on Groundwater Status and Trend Assessment). A number of recommendations for technical users of the report are highlighted in boxes in each Chapter. The common themes from these recommendations are collated in Chapter 8, as issues and questions to WGGW and MS in general. The key message from this is the need for closer interaction between scientific disciplines, practitioners and Working Groups in developing conceptual understanding for GWAAEs and implementation of WFD requirements, including identification of GWAAEs, their characterisation and monitoring, and adopting appropriate status assessment methodologies. [less ▲]

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See detailMéthodologie de diagnostic environnemental autour de captages d’eau potabilisable sensibles qualitativement du point de vue nitrate
Vandenberghe, Christophe ULiege; Bah, Boubacar Billo ULiege; Orban, Philippe ULiege et al

Report (2015)

Le projet s’inscrit dans le cadre des « contrats de captages » dont la mise en oeuvre est assurée par la SPGE (Société Publique de Gestion de l’Eau) et ce, conformément au contrat de gestion qui lie cette ... [more ▼]

Le projet s’inscrit dans le cadre des « contrats de captages » dont la mise en oeuvre est assurée par la SPGE (Société Publique de Gestion de l’Eau) et ce, conformément au contrat de gestion qui lie cette dernière avec le Gouvernement wallon. L’objectif se décline en trois phases : 1. établir une méthodologie commune de détermination et priorisation des actions à entreprendre autour de captages en vue d’y préserver ou de restaurer la qualité de l’eau ; 2. tester la méthodologie (définition des actions à entreprendre) sur six situations jugées représentatives sur des captages de la SWDE (Société Wallonne des Eaux) ; 3. proposer et coordonner des actions à mettre en oeuvre sur deux ou trois des six sites pilotes. La méthodologie est traduite en logigrammes d’actions qui proposent des démarches communes de diagnostic et d’actions à entreprendre autour de captages en vue d’y préserver ou de restaurer la qualité de l’eau. [less ▲]

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See detailUse of dual carbon-chlorine isotope analysis to identify degradation pathways of 1,1,1-trichloroethane in groundwater
Palau, Jordi; Jamin, Pierre ULiege; Badin, Alice et al

Conference (2015, September 17)

The high susceptibility of chlorinated aliphatic hydrocarbons (CAHs) like 1,1,1-trichloroethane (1,1,1-TCA) to be transformed via different competing pathways (biotic and abiotic) complicates the ... [more ▼]

The high susceptibility of chlorinated aliphatic hydrocarbons (CAHs) like 1,1,1-trichloroethane (1,1,1-TCA) to be transformed via different competing pathways (biotic and abiotic) complicates the assessment of their fate in groundwater. This knowledge is necessary to evaluate contaminant degradation and potential formation of toxic intermediates. Identifying pathways is further complicated in sites contaminated by mixed CAHs because some degradation products of 1,1,1-TCA can be formed from different precursors. Here, identification of pathways based solely on substrate-product concentration relationships may lead to ambiguous interpretations. This study investigates, for the first time, dual C−Cl isotope fractionation as a means of identifying and assessing degradation pathways of 1,1,1-TCA in groundwater. Distinctly different dual isotope trends (L = Δδ13C/Δδ37Cl) were observed for 1,1,1-TCA transformation via oxidation with heat-activated persulfate (L = ∞), reduction with zerovalent iron (L = 1.5 ± 0.1), hydrolysis and dehydrohalogenation (HY/DH, L = 0.33 ± 0.04) in laboratory experiments, illustrating the potential of a dual isotope approach. This approach was evaluated in an aerobic aquifer impacted by 1,1,1-TCA and trichloroethylene (TCE) with concentrations of up to 20 mg/L and 3.4 mg/L, respectively. For 1,1,1-TCA, the dual isotope slope determined from field samples (L = 0.6 ± 0.2, r2 = 0.75) was close to the slope observed for HY/DH in the laboratory (L = 0.33 ± 0.04), indicating that HY/DH was the predominant degradation pathway of 1,1,1-TCA in the aquifer. The observed deviation could be explained by a minor contribution of additional degradation processes. This result, along with the little degradation of TCE determined from isotope measurements, confirmed that 1,1,1-TCA was the main source of the 1,1-dichlorethylene (1,1-DCE) detected in the aquifer with concentrations of up to 10 mg/L. This study demonstrates that a dual C-Cl isotope approach can strongly improve the qualitative and quantitative assessment of 1,1,1-TCA degradation processes in the field. [less ▲]

Detailed reference viewed: 49 (10 ULiège)